Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (4): 423.

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Studies on Condensation Reaction of Methyldiphlorosilane

Qiu Huayu, Du Zuodong   

  1. Department of Chemistry, Shandong University, Jinan
  • Received:1987-11-14 Online:1989-04-24 Published:1989-04-24

Abstract: The condensation reaction of methyldichlorosilane in mixed solvents with different proportion of toluene and dioxane via various coupling reagents (Na,K,Li or Na/Kalloy) were studied in detail. The effect of reaction temperature and time was also suggested. The structure of polysilane obtained from coupling of MeHSiCl2by Na/Kalloy in THF may be chain-cyclic form.

Key words: Methyldichlorosilane, Condensation, Polysilane

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