Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (11): 1171.

• Articles •     Next Articles

Synthesis and Identification of GeFeAPO-5 Molecular Sieve

Han Shuyun1, Wang Liqun2, Yu Guirong2   

  1. 1. Department of Chemistry, Qingdao University, Qingdao, 266071;
    2. Department of Chemistry, Jilin University, Changchun
  • Received:1989-01-17 Online:1990-11-24 Published:1990-11-24

Abstract: GeFeAPO-5 molecular sieve was synthesized in the system of fluoride ions. After adsorption of pyridine the IRspectra showed the presence of both Brönsted and Lewis acid sites. GeFeAPO-5 molecular sieve was identified by means of X-ray diffraction analysis, determination of the unit cell parameters, electron probe, infrared spectra, Mössbauer spectroscopy, electron paramagnetic resonance spectrum, high resolution magic-angle-spinning solid state 31P and 27Al nuclear magnetic resonance. The results showed Fe and Ge entered into the GeFeAPO-5 framework.

Key words: Molecular sieve, Aluminophosphate, Germanium, Iron

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