Synthesis of AM/AMPS/N8AM Tercopolymer in Ionic Liquids and Performance of the Polymer Solution

Chem. J. Chinese Universities

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Synthesis of AM/AMPS/N8AM Tercopolymer in Ionic Liquids and Performance of the Polymer Solution

DING Wei¹*, LIU Hai-Yan^1,2, YU Tao¹, QU Guang-Miao¹

1. College of Chemistry and Chemical Engineering, Daqing Petroleum Institute, Daqing 163318;
2. Chemistry Department, Daqing Teacher’s College, Daqing 163712

Received:2007-11-20 Revised:1900-01-01 Online:2008-04-10 Published:2008-04-10
Contact: DING Wei

Abstract

Abstract: The tercopolymer AM-AMPS-N8AM was prepared through radical polymerization with 1-butyl-3-methyl imidazolium tetrafluoroborate ionic liquids as the reaction medium of polymerization, benzoperoxide/N,N-dimethylaniline(BPO/DMA) redox system as the initiator, acrylamide(AM) and 2-acrylamido-2-methylpropane sulfonic acid(AMPS) as the hydrophilic monomer, N-octylacrylamide(N8AM) as the hydraphobic monomer. The structure of polymer was identified by ¹H NMR, ¹³C NMR and element analysis. The apparent viscosity of the terpolymer aqueous solution is measured, and the result shows that the terpolymer synthesized in ionic liquids has an excellent tackifying ability.When the mass concentration of solution is 1.2 g/L, the apparent viscosity can reach 220.1 mPa·s, when the temperature changes from 45 ℃ to 90 ℃, the viscosity remaining rate is 65% and when the shear rate increases to 24.48 s^-1, the viscosity remaining rate is 43.5%. It is shown that the tercopolymer solution has better temperature tolerance and shearing resistance

Key words: Ionic liquids, Hydrophobically association, Acrylamide, Terpolymerization

CLC Number:

O631.5

TrendMD:

DING Wei¹*, LIU Hai-Yan^1,2, YU Tao¹, QU Guang-Miao¹. Synthesis of AM/AMPS/N8AM Tercopolymer in Ionic Liquids and Performance of the Polymer Solution[J]. Chem. J. Chinese Universities, doi: .

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Synthesis of AM/AMPS/N8AM Tercopolymer in Ionic Liquids and Performance of the Polymer Solution

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