The Electrocatalytic Oxidation of Ascorbic Acid on Nickel Hexacyanoferrate Film Modified Electrode

Abstract

Abstract: The nickel hexacyanoferrate (NiHCF) film modified electrode was made by electrochemically depositing method.The electrocatalytic oxidation of ascorbic acid (AH₂) on the electrode was described.The oxidation peak potential shifts negatively 300 mV.The modified electrode can be used for determination of ascorbic acid in the concentration range of 1.0× 10^-7～1.0×10^-2 mol/L.This method has been applied successfully to the analysis of ascorbic acid in fruits and vegetables.

Key words: Nickel hexacyanoferrate, Chemically modified electrode, Ascorbic acid

TrendMD:

WANG Sheng-fu, JIANG Mian, ZHOU Xing-yao . The Electrocatalytic Oxidation of Ascorbic Acid on Nickel Hexacyanoferrate Film Modified Electrode[J]. Chem. J. Chinese Universities, 1992, 13(3): 325.

[1]	ZHAI Chen, PENG Yankun, LI Yongyu, ZHAO Juan. Detection of Chemical Additives in Food Using Raman Chemical Imaging System^† [J]. Chem. J. Chinese Universities, 2017, 38(3): 369.
[2]	LIU Shumin, ZHENG Yudong, LI Wei, SUN Yi, YUE Lina, ZHAO Zhenjiang. Preparation and Electrochemical Performance of 3D-nanohole PVA/a-MWCNTs Hydrogel Electrode Membrane^† [J]. Chem. J. Chinese Universities, 2016, 37(2): 290.
[3]	YANG Shuang, JI Xiaohui, YANG Wensheng. Mechanism in the Preparation of Gold Nanoflowers by Ascorbic Acid Reduction^† [J]. Chem. J. Chinese Universities, 2016, 37(12): 2125.
[4]	LI Chong, JIA Liping, MA Rongna, JIA Wenli, WANG Huaisheng, YANG Haitao, GUO Aixiang. Simultaneous Detection of Ascorbic Acid, Dopamine, Uric Acid and Tryptophan on the PEI-graphene Modified Electrode^† [J]. Chem. J. Chinese Universities, 2015, 36(7): 1282.
[5]	MA Yongjun, DING Jing, JIN Zhimei, TIE Zhenzhen, ZHOU Min. Inhibiting Effect of Chloride Ion for the Electro-oxidation Reaction of Four Organic Alcohols on a Chemically Modified Platinum Anode^† [J]. Chem. J. Chinese Universities, 2015, 36(5): 864.
[6]	LIN Hai-Lian, YANG Jian-Mao, LIU Jian-Yun, XIAO Jian-Lin, ZHANG Xin. Preparation of Palladium Nanoparticle/Polyaniline Multilayer Films for the Determination of Dopamine and Ascorbic Acid [J]. Chem. J. Chinese Universities, 2013, 34(5): 1099.
[7]	SANG Xiao-Guang, ZENG Fan-Wu, LIU Xiao-Xia. Preparation and Electrochemical Properties of Polyaniline Nanofiber Modified Graphite Foil [J]. Chem. J. Chinese Universities, 2012, 33(06): 1312.
[8]	ZHANG Li-Pei, HU Bo, WANG Jian-Hua*. Detection of Ascorbic Acid by Quantum Fluorescence Probe [J]. Chem. J. Chinese Universities, 2011, 32(3): 688.
[9]	SU Bi-Quan, ZHANG Yu-Zhen, DU Yong-Ling, WANG Chun-Ming*. Fabrication of a Silver Nanoparticle/polydopamine Modified Glassy Carbon Electrode and Its Electrocatalytic Reduction for p-Nitrophenol [J]. Chem. J. Chinese Universities, 2010, 31(8): 1661.
[10]	SHAO Feng-Wei, CAI Yu-Rong, YAO Ju-Ming*. Porous Hydroxyapatite Nanoparticles as a Carrier of Ascorbic Acid [J]. Chem. J. Chinese Universities, 2010, 31(6): 1093.
[11]	YANG Shao-Ming*, WEI Zhi-Peng, HU Guang-Hui, JIANG Dan, HUANG Ai-Hua, .... Simultaneous Determination of Catechol and Hydroquinone at a Carbon Nanotubes Modified Electrode [J]. Chem. J. Chinese Universities, 2010, 31(2): 264.
[12]	LIU Jing-Li1, GUO Yong^1, XUE Ying^1,2, YAN Guo-Sen^1. Theoretical Investigation on the Vibrational Spectra of Dehydroascorbic Acid [J]. Chem. J. Chinese Universities, 2009, 30(1): 100.
[13]	ZHANG Dong-Mei¹, ZHOU Nan-Di¹, ZHOU Hui¹, CHEN Ting², LI Gen-Xi¹*. Electrochemical Study of the Inhibitory Effect of Sinapic Acid and Its Derivatives on Tyrosinase Reactivity [J]. Chem. J. Chinese Universities, 2008, 29(2): 273.
[14]	ZHOU Hong, SUN Chang-Qing^*. Fabrication and Electrocatalysis of Multilayer Film Electrodes Based on MWCNTs@CHIT-Fc Composites [J]. Chem. J. Chinese Universities, 2008, 29(11): 2159.
[15]	LI Ya-Zuo, ZHANG Su-Xia, LI Xiao-Fang, SUN Chang-Qing . Fabrication of Chemically-modified Electrode Containing Poly(allylamine)ferrocene Based on Sol-gel Technique and Its Electrocatalytic Oxidation of Ascorbic Acid [J]. Chem. J. Chinese Universities, 2003, 24(8): 1373.

The Electrocatalytic Oxidation of Ascorbic Acid on Nickel Hexacyanoferrate Film Modified Electrode

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments