The Synthesis and Crystal Structure of a Trigonal-Planar Complex of Zinc [Bu4N][Zn(SC6H2Pr3i-2,4,6)3]·PriOH

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (4): 441.

• Articles • Previous Articles Next Articles

The Synthesis and Crystal Structure of a Trigonal-Planar Complex of Zinc [Bu₄N][Zn(SC₆H₂Pr₃ⁱ-2,4,6)₃]·PrⁱOH

TANG Ka-luo, LI Ai-qun, JIN Xiang-lin, TANG You-qi

Institute of Physical Chemistry, Peking University, Beijing, 100871

Received:1992-01-11 Online:1992-04-24 Published:1992-04-24

Abstract

Abstract: The title complex was prepared and structurally characterized.The crystal belongs to space group P2₁/c, a= 1.4335(8) nm, b=2.4389(16) nm, c = 2.0556(12)nm, β=105.91 (5)°, V=6.911(7) nm³, D_c ==1.031 g/cm³ for Z = 4,R=0.076.R_w = 0.072 for 3846 reflections.The zinc is trigonal-planar coordinate.The average Zn-S bond length is 0.246 nm.

Key words: Zinc complex, Synthesis, Crystal structure, Trigonal-planar coordination, 2,4,6-Tri-isopropylthiophenol

TrendMD:

TANG Ka-luo, LI Ai-qun, JIN Xiang-lin, TANG You-qi . The Synthesis and Crystal Structure of a Trigonal-Planar Complex of Zinc [Bu₄N][Zn(SC₆H₂Pr₃ⁱ-2,4,6)₃]·PrⁱOH[J]. Chem. J. Chinese Universities, 1992, 13(4): 441.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[3]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[4]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[5]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[6]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[7]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[8]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[9]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.
[10]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[11]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[12]	ZHUANG Jiahao, WANG Dingsheng. Current Advances and Future Challenges of Single-atom Catalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220043.
[13]	FENG Li, SHAO Lanxing, LI Sijun, QUAN Wenxuan, ZHUANG Jinliang. Synthesis of Ultrathin Sm-MOF Nanosheets and Their Visible-light Induced Photodegradation of Mustard Simulant [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210867.
[14]	ZHANG Zhinan, CHENG Haiming, TENG Shiyong, ZHANG Ying. Synthesis and Optical Properties of RbPb₂Cl₅ [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220418.
[15]	XING Peiqi, LU Tong, LI Guanghua, WANG Liyan. Controllable Syntheses of Two Cd（II） Metal-organic Frameworks Possessing Related Structures [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220218.

The Synthesis and Crystal Structure of a Trigonal-Planar Complex of Zinc [Bu₄N][Zn(SC₆H₂Pr₃ⁱ-2,4,6)₃]·PrⁱOH

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments