Effects of Ag+, Sr2+, Yb3+ Dual-doping on Thermoelectric Properties of Ca3Co4O9-δ

doi:10.7503/cjcu20170244

Abstract

Abstract:

A series of ceramic materials, Ca_3-x-yAg_xSr_yCo₄O_9-δ, Ca_3-x-zAg_xYb_zCo₄O_9-δ and Ca_3-y-zSr_yYb_zCo₄O_9-δ(x, y, z=0.1, 0.15, 0.2) which worked from 300 K to 870 K with excellent thermoelectric properties, was prepared by sol-gel and cold-pressing method. The XRD, IR and SEM results reveal that the prepared samples are uniform crystal particles with high purity. Ag⁺, Sr²⁺ and Yb³⁺ ions have replaced the position of Ca²⁺ ions and they are dissolved in the crystal, which changes the cell volume of the dual-doping materials but does not change the crystal symmetric structure. The characterization results of resistivity and Seebeck coefficient reveal that the concentration of carrier is optimized by dual doping, accordingly the resistivity decreases continuously with the doped different materials and the value of Seebeck coefficient increases continuously with the doped different materials. It can be concluded from the calculations that the electron effective mass contributes to the increase of Seebeck coefficient. The characterization results of thermal conductivity indicate that the thermal conductivity of dual doped samples decreases with the increase of temperature, and the phonon thermal conductivity still contributes more in the prepared system, which is consistent with the results of Ag⁺, Sr²⁺, Yb³⁺ single doped Ca₃Co₄O_9-δ samples. The figure of metrt ZT of Ca_2.7Ag_0.2Yb_0.1Co₄O_9-δ exceeds 0.18 at 870 K.

Key words: Dual doping, Sol-gel process, Thermoelectric property, Ceramics

CLC Number:

O611.6

TrendMD:

YANG Tao, CHENG Tiexin, ZHOU Guangdong. Effects of Ag⁺, Sr²⁺, Yb³⁺ Dual-doping on Thermoelectric Properties of Ca₃Co₄O_9-δ[J]. Chem. J. Chinese Universities, 2017, 38(8): 1309.

References

[1] Zhang X., Ma X. Y., Zhang F. P., Wu P. X., Lu Q. M., Liu Y. Q., Zhang J. X., Acta Phys. Sin., 2012, 61(4), 396-401(张忻, 马旭颐, 张飞鹏, 武鹏旭, 路清梅, 刘燕琴, 张久兴. 物理学报, 2012, 61(4), 396-401)
[2] Heremans P. J., Jovovic V., Toberer S. E., Saramat A., Kurosaki K., Charoenphakdee A., Yamanaka S., Snyder J. G., Science, 2008, 321(5888), 554-557
[3] He Y., Lu P., Shi X., Xu F. F., Zhang T. S., Liu H. L., Chen L. D., Snyder J. G., Adv. Mater., 2014, 27(24), 3639-3644
[4] Zhang Q., Sun Y. M., Xu W., Zhu D. B., Adv. Mater., 2014, 26(40), 6829-6851
[5] Liang A. S., Li J. J., Pan C. J., Wang L., Chem. J. Chinese Universities, 2016, 37(6), 1161-1167(梁安生, 李俊杰, 潘成军, 王雷. 高等学校化学学报, 2016, 37(6), 1161-1167)
[6] Ohta H., Mune Y., Koumoto K., Mizoguchi T., Ikuhara Y., Nat. Mater., 2007, 516(17), 5916-5920
[7] Bin Z., Lan J. L., Lin Y. H., Rare Metal Mat. Eng., 2013, 42, 54-56
[8] Zhu X. B., Shi D. Q., Dou S. X., Sun Y. P., Li Q., Wang L., Li W. X., Yeoh W. K., Zheng R. K., Chen Z. X., Kong C. X., Acta Mater., 2010, 58, 4281-4288
[9] Zhang Q., Sun Y. M., Xu W., Zhu D. B., Adv. Mater., 2014, 26(40), 6829-6851
[10] Wu Z. H., Xie H. Q., Zhai Y. B., Gan L. H., Liu J., Chin. Phys. B, 2015, 24(3), 214-217
[11] Ohtaki M., Araki K., Yamamoto K., J. Electron. Mater., 2009, 38(7), 1234-1238
[12] Ren G. K., Lan J. L., Zeng C. C., Liu Y. C., Zhan B., Butt S. J., Lin Y. H., Nan C. W., Jom., 2015, 67(1), 211-221
[13] Liu D., Pu Y. P., Shi X., Vacuum, 2012, 86(10), 1568-1571
[14] Lubeck C. R., Han T. Y. J., Gash A. E., Satcher J. H., Doyle F. M., Adv. Mater., 2006, 18(6), 781-784
[15] Yu H. J., Jeong M., Lim Y. S., Seo W. S., Kwon O. J., Park C. H., Hwang H. J., RSC Adv., 2014, 4(16), 43811-43814
[16] Miclau M., Hebert S., Retoux R., Martin C., J. Solid State Chem., 2005, 178(4), 1104-1111
[17] Wang Y., Sui Y., Cheng J. G., Wang X. J., Su W. H., J. Alloy. Compd., 2009, 477(1/2), 817-821
[18] Constantinescu G., Rasekh S., Torres M. A., Diez J. C., Madre M. A., Sotelo A., J. Alloy. Compd., 2013, 577, 511-515
[19] Xu J., Wei C. P., Jia K., J. Alloy. Compd., 2010, 500(2), 227-230
[20] Limelette P., Hardy V., Auban-Senzier P., Jérome D., Flahaut D., Hébert S., Frésard R., Simon C., Noudem J., Maignan A., Phys. Rev. B, 2005, 71(23), 233108-233112
[21] Wang Y., Sui Y., Su W. H., J. Appl. Phys., 2008, 104(1), 135-142
[22] Wang Y., Sui Y., Fan H. J., Wang X. J., Su Y. T., Su W. H., Liu X. Y., Chem. Master., 2009, 21(19), 4653-4660
[23] Wang Y., Sui Y., Wang X. J., Su W. H., Appl. Phys. Lett., 2010, 97(5), 052109-052112

Related Articles 15

[1]	WANG Yihan,YIN Qiang,DU Kai,YIN Qinjian. Polypyrrole/Polyaniline Nanocomposite Nanotubes with Enhanced Thermoelectric Properties ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 175.
[2]	DU Yifan, AI Chaoqian, ZHANG Yaoyao, WANG Wei. Preparation and Quasi-superhydrophobic Properties of the Surface of Mullite Whiskers/Cordierite ^† [J]. Chem. J. Chinese Universities, 2019, 40(9): 1955.
[3]	YANG Tao, CHENG Tiexin, ZHOU Guangdong. Effects of Ag or Yb Doping on Thermoelectric Properties of Ca₃Co_3.9Cu_0.1 $O 9 - δ †$ [J]. Chem. J. Chinese Universities, 2017, 38(3): 335.
[4]	HE Yannan, YU Zhiqiang. Effect of Surface Organic Functional Modification of ZrB₂ Nanosize Multiphase Ceramics on the Thermal Properties of Its Composites^† [J]. Chem. J. Chinese Universities, 2015, 36(9): 1846.
[5]	ZHU Yi-Hua, WANG Hao, SHAO Chang-Wei. Synthesis and Characterization of SiC Ceramic Precursor with High Boron Content [J]. Chem. J. Chinese Universities, 2013, 34(10): 2415.
[6]	LI Bo, ZHANG Hui-Jie, LIAO Xiao-Ling, ZHU Xiang-Dong, FAN Hong-Song, ZHANG Xing-Dong. Effects of Microstructure of Calcium Phosphate Ceramics Particles on Protein Adsorption [J]. Chem. J. Chinese Universities, 2012, 33(03): 447.
[7]	LUO Min*, LIANG Jun, FANG Jun-Zhuo, WANG Zheng. Growth of Silicalite-2 Zeolite Film in Microchannels of Biomorphic Porous SiC Ceramics [J]. Chem. J. Chinese Universities, 2009, 30(7): 1279.
[8]	ZHANG Hong-Bo¹, SU Chun-Hui^1,2*, WANG Yi-Min¹, SHAO Jing¹, XU Su-Lian¹, ZHU Xiao-Wei², ZHANG Hua-Shan¹. Preparation and Characterization of Neodymium-doped Oxyfluoride Glass-ceramics [J]. Chem. J. Chinese Universities, 2008, 29(4): 677.
[9]	QU Yang, LI Zhen-Sheng, YANG Bang-Cheng*, ZHANG Xing-Dong. Studies on the Bioactivity of Osteoblasts on the Surfaces of Nano-TiO₂ Ceramics [J]. Chem. J. Chinese Universities, 2007, 28(7): 1288.
[10]	HAO Su-E, SUN Liang, HUANG Jin-Xiang, WEI Yong-De. NTCR Effect of BaTiO₃-based PTC Ceramics Penetrated by Rare Earth [J]. Chem. J. Chinese Universities, 2005, 26(12): 2207.
[11]	HAO Su-E, SUN Liang, HUANG Jin-Xiang, WEI Yong-De. NTCR Effect of BaTiO₃-based PTC Ceramics Penetrated by Rare Earth [J]. Chem. J. Chinese Universities, 2005, 26(12): 2207.
[12]	FENG Cai-Hong, JIAO Qing-Ze, LI Qian-Shu, MING En-Ze . Preparation of PES-SiO₂ Hybrids Through Sol-gel Method [J]. Chem. J. Chinese Universities, 2004, 25(9): 1743.
[13]	JU Wei-Gang, ZHANG Xiao-Hong, WU Shi-Kang . Preparation of TiO₂ Nano-materials Using Gelator Aggregation as Template and Its Properties [J]. Chem. J. Chinese Universities, 2004, 25(12): 2308.
[14]	LIU Wei, ZHANG Ya-Hong, GUO Na, ZHAO Yi-Yang, HAO Xiu-Feng, ZHANG Wan-Jin, WANG Ce {1}, WEI Yen . Preparation of Mono-component Silica Monolith via the Improved Bulk Sol-gel Process [J]. Chem. J. Chinese Universities, 2003, 24(3): 519.
[15]	QI Kai, YANG Zhen-Zhong, YANG Yun-Xin, ZHAO De-Lu. Surfactant-template Synthesis of Mesoporous Silica Monolith via Fast Sol-gel Process [J]. Chem. J. Chinese Universities, 2002, 23(2): 339.

Effects of Ag⁺, Sr²⁺, Yb³⁺ Dual-doping on Thermoelectric Properties of Ca₃Co₄O_9-δ

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments