Synthesis,  Structure and Si—Si Bond Stability of η6-[Tris(trimethylsilyl)phenylsilane]tricarbonylmolybdenum Complexes

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (7): 1537.

• Preface • Previous Articles Next Articles

Synthesis, Structure and Si—Si Bond Stability of η6-[Tris(trimethylsilyl)phenylsilane]tricarbonylmolybdenum Complexes

LIU Qiu-Hua, SUN Huai-Lin

State Key Laboratory of Elemento\|organic Chemistry, Department of Chemistry, Nankai University, Tianjin 300071, China

Received:2010-09-02 Revised:2010-10-16 Online:2011-07-10 Published:2011-06-02
Contact: Huai-Lin SUN E-mail:sunhl@nankai.edu.cn
Supported by:
国家自然科学基金(批准号: 20834002)、天津市自然科学基金(批准号: 08JCZDJC21600)及高等学校博士学科点专项科研基金(批准号: 20090031110012)资助.

Abstract

Abstract: Tris(trimethylsilyl)phenylsilane, (SiMe3)3SiC6H4R (R = H, p-Me and p-MeO), reacted with tripyridine(tircarbonyl)molybdenum in the presence of BF3, giving corresponding ?6-[tris(trimethylsilyl)phenylsilane]tricarbonylmolybdenum complexes, ?6-[(SiMe3)3SiC6H4R]Mo(CO)3. The new complexes were characterized by 1H、13C NMR、IR and elemental analysis. The molecular structure of ?6-[(SiMe3)3SiC6H4R]Mo(CO)3 (R = H) has been determined by the X-ray diffraction method. The Si-Si bonds in the complexes were found to be stable towards the intramolecular transition metal atom.

Key words: Polysilanyl, Carbonylmolybdenum, h6-phenyl complex, X-ray diffraction

TrendMD:

LIU Qiu-Hua, SUN Huai-Lin. Synthesis, Structure and Si—Si Bond Stability of η6-[Tris(trimethylsilyl)phenylsilane]tricarbonylmolybdenum Complexes[J]. Chem. J. Chinese Universities, 2011, 32(7): 1537.

[1]	ZHANG Yongpo, ZHANG Yang, SUN Huailin. Stereo Selective Synthesis and Absolute Configuration Determination of (2E,4S)-4-(t-butoxycarbonylamino)-5-[(3S)-2'-oxo-3'-pyrrolidinyl]-2-pentenoic Acid Ethyl Ester^† [J]. Chem. J. Chinese Universities, 2014, 35(2): 292.
[2]	LÜ Haoting, LIU Tingting, ZHANG Mingtao, LIU Jie, SUN Huailin. Synthesis of η⁶-[Tris(trimethylsilyl)phenylsilane]tricarbonylchromium Complexes and Theoretical Studies on the Possible Interaction of Intermolecular Si—Si Bonds and Chromium Centers^† [J]. Chem. J. Chinese Universities, 2014, 35(11): 2341.
[3]	LIU Hao, XU Fen, SUN Li-Xian, CAO Zhong, ZHOU Huai-Ying. Preparation and Hydrogen Generation for Al-LiBH₄ Composite Materials [J]. Chem. J. Chinese Universities, 2013, 34(8): 1953.
[4]	SHAO Chun-Guang, ZHUO Ran-Ran, LI Qian, CAO Wei, ZHANG Yang, ZHANG Rui-Jing, LIU Cheng-Gang, SHEN Chang-Yu. Relationship Between Crystal Orientation and Stress-induced Crystalline Melting of Syndiotactic Polypropylene Under Uniaxial Deformation via in situ Wide-angle X-ray Scattering [J]. Chem. J. Chinese Universities, 2013, 34(2): 485.
[5]	ZHOU Jing, LI Liang, HUANG Feng-Xian, SHEN Hong-Zhi, YANG Hang, ZHOU Qiang, WANG Wen-Quan, XU Da-Peng. In-situ Raman Spectra and X-ray Diffraction Study on Pressure-induced Phase Transition in Columbite ZnNb₂O₆ [J]. Chem. J. Chinese Universities, 2013, 34(10): 2383.
[6]	GUO Xing-Yuan, DING Zhan-Hui, ZHAO Xu-Dong, QIU Li-Xia, XUE Yan-Feng, .... Influence of Excitation Intensities on Photoluminescence of ZnO(Wurtzite) Whiskers at Room Temperature [J]. Chem. J. Chinese Universities, 2010, 31(2): 243.
[7]	ZHENG Yi-Fan, LIU Hua-Zhang, LI Xiao-Nian. In situ X-ray Diffraction Investigation on Reduction Process of Ammonia-synthesis Fused-iron Catalysts and the Formation Mechanism of Its Active Phase [J]. Chem. J. Chinese Universities, 2009, 30(6): 1177.
[8]	SHI Shu-Yun^1,2, ZHAO Yu², ZHANG Yu-Ping¹, HUANG Ke-Long¹, LIU Su-Qin¹. Separatian and Identification of Constituents from Ligularia atroviolacea* [J]. Chem. J. Chinese Universities, 2008, 29(5): 941.
[9]	SUN Feng-Mei, SHI De-Qing, TIAN Man-Man, TAN Xiao-Song. Synthesis and Biological Activities of 2-oxo-2-[1-(3-pyridylmethylamino)-1'-aryl]methyl-4-aryl-5,5-dimethyl-1,3,2-dioxaphosphinane [J]. Chem. J. Chinese Universities, 2006, 27(11): 2092.
[10]	GUO Xing-Yuan¹, YU Ying-Ning², XU Da-Peng¹, DING Zhan-Hui¹, SU Wen-Hui^1,3,4. Growth of ZnO(Wurtzite) Whiskers Using the Floating Zone Method at High Oxygen Pressure [J]. Chem. J. Chinese Universities, 2006, 27(10): 1811.
[11]	LIU Lei-Jing, GENG Jian-Xin, ZHOU Yun-Chun, YIN Li, LI Gao, ZHOU En-Le, Jacky Lam Wing Yip, Tang Ben-Zhong. Crystal Structure of 5[(4'-Heptoxy-biphenylyl-4-yl)oxy]carbonyl-1-pentyne [J]. Chem. J. Chinese Universities, 2005, 26(7): 1366.
[12]	ZHANG Sheng-Mao, ZHANG Zhi-Jun, DANG Hong-Xin, LIU Wei-Min, XUE Qun-Ji . Preparation and Characterization of Orderly Alternating TiO₂/CTAB Multilayer Film [J]. Chem. J. Chinese Universities, 2003, 24(6): 1136.
[13]	LU Yi, ZHU Zhen-Ping, WU Wei-Ze, LIU Zhen-Yu . Preparation of Carbon Nanotubes by Catalysis-assisted Detonation [J]. Chem. J. Chinese Universities, 2003, 24(6): 1063.
[14]	WANG Wen-Quan, FU Quan, SU Feng, WANG Xue-Feng, YAN Yu, JIN Han-Min. Structure and Magnetic Properties of Compounds YCo_12-xTi_x and YFe_12-xTi_x [J]. Chem. J. Chinese Universities, 2003, 24(2): 288.
[15]	JIAN Fang-Fang, WEN Li-Rong, LI Xue-Mei, ZHANG Shu-Sheng, JIAO Kui . Synthesis and Crystal Structure of 2,3,4,6-Tetra-O-acetyl-(β-D-glycosyl)-isothiocyanate [J]. Chem. J. Chinese Universities, 2003, 24(1): 58.

Synthesis, Structure and Si—Si Bond Stability of η6-[Tris(trimethylsilyl)phenylsilane]tricarbonylmolybdenum Complexes

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments