Preparation and Characterization of Hydroxyl Functional Compound with Covalent Organic Framework

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (6): 1234.

• Articles • Previous Articles Next Articles

Preparation and Characterization of Hydroxyl Functional Compound with Covalent Organic Framework

PEI Cui-Ying, QU Feng-Yu*

College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, China

Received:2010-11-10 Revised:2011-03-01 Online:2011-06-10 Published:2011-05-10
Contact: QU Feng-Yu E-mail:qufengyu@hrbnu.edu.cn
Supported by:
国家自然科学基金(批准号: 20871037)资助.

Abstract

Abstract: A microporous covalent organic framework (COF) has been designed and synthesized via nickel (0)-catalyzed Yamamoto-type Ullmann cross-coupling reaction. Tri(4-bromophenyl)silanol has been employed as monomer and the structure was determined using MAS NMR, FTIR, SEM and PXRD. The functional structure exhibits not only high thermal stability （467 ℃），high chemical stability but also large surface area (958 m2g-1), and the pore size is 1.27 nm.

Key words: covalent organic frameworks(COFs), microporous polymer, Ullmann reaction, thermal and chemical stability, Chemical stability, hydroxyl functional structure

CLC Number:

TrendMD:

PEI Cui-Ying, QU Feng-Yu*. Preparation and Characterization of Hydroxyl Functional Compound with Covalent Organic Framework[J]. Chem. J. Chinese Universities, 2011, 32(6): 1234.

[1]	YAN Yanhong, WU Simin, YAN Yilun, TANG Xihao, CAI Songliang, ZHENG Shengrun, ZHANG Weiguang, GU Fenglong. Sulfonic Acid-functionalized Spherical Covalent Organic Framework with Ultrahigh Capacity for the Removal of Cationic Dyes [J]. Chem. J. Chinese Universities, 2021, 42(3): 956.
[2]	XU Guojie, CHANG Jianhong, FANG Qianrong. 2D Mesoporous Covalent Organic Framework with High Iodine Capture Capability [J]. Chem. J. Chinese Universities, 2020, 41(12): 2667.
[3]	LIU Xiaozhou, GUAN Xinyu, FANG Qianrong, JIN Yongri. Three-dimensional Covalent Organic Frameworks Synthesized by Room Temperature Ionic Liquid Method^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1341.
[4]	HUANG Weiwei, REN Jiawang, FANG Qianrong, Valentin VALTCHEV. Synthesis of Zeolite β@IISERP-COF2 Core-shell Hybrid Materials^† [J]. Chem. J. Chinese Universities, 2018, 39(6): 1127.
[5]	YOU Yanwei, XIAO Changfa, WANG Chun, HUANG Qinglin, CHEN Mingxing, HUANG Yan. Preparation and Properties of Poly(tetrafluoroethylene-co-hexafluoropropylene) Hollow Fiber Membranes^† [J]. Chem. J. Chinese Universities, 2017, 38(9): 1678.
[6]	LIU Tingzhi, XIA Jieren, LI Yao, CHEN Wenkai, ZHANG Shuai, LIU Yi, ZHENG Li, YANG Yunhui. Preparation of Label-free C-Reactive Protein Immunosensor Based on the Palladium-coordinated Covalent Organic Frameworks(Pd/COF-LZU1) Material^† [J]. Chem. J. Chinese Universities, 2015, 36(10): 1880.
[7]	ZHANG Ying-Peng, ZHANG Wei-Na, YANG Yun-Shang, QIAO Ming. Total Synthesis of Natural Product Luxenchalcone [J]. Chem. J. Chinese Universities, 2013, 34(12): 2734.
[8]	GUAN You-Wei, BEN Teng, ZHANG Da-Liang, XU Jun, PEI Cui-Ying, ZHU Liang-Kui, LU Chun-Jing, MENG Fan-Xing, DENG Feng, QIU Shi-Lun. Synthesis and Gas Storage of Porous Poly (phenyl ether) [J]. Chem. J. Chinese Universities, 2012, 33(10): 2152.
[9]	ZHANG Ying-Peng*, CHEN Yu-Tao, YANG Yun-Shang, GUAN Xiao. Modified Total Synthesis of Verbenachalcone [J]. Chem. J. Chinese Universities, 2010, 31(7): 1342.
[10]	CHEN Zuo-Feng, JIANG Yan-Xia, XU Jin-Mei, ZHUANG Quan-Chao, HUANG Ling, DONG Quan-Feng, SUN Shi-Gang. Compatibility of a Novel Composite Microporous Polymer Electrolyte with Anode of Li-ion Batteries [J]. Chem. J. Chinese Universities, 2006, 27(10): 1937.
[11]	LI Yong-Guo, LIU Hong, WANG Zheng-Tao, HU Zhi-Bi. Multi-components Comprehensive Evaluation on Chemical Stability of Fermented Red Yeast Rice [J]. Chem. J. Chinese Universities, 2006, 27(1): 35.
[12]	YANG Jia-Zhen, JIN Yi, CAO Ying-Hua, SUN Li-Xian, TAN Zhi-Cheng . Studies on Electrochemical Stability of Room Temperature Ionic Liquids [J]. Chem. J. Chinese Universities, 2004, 25(9): 1733.

Preparation and Characterization of Hydroxyl Functional Compound with Covalent Organic Framework

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 12

Recommended Articles

Metrics

Comments