Preparation of LiNi0.5Mn1.5O4 as 5 V Cathode Materials for Lithium Ion Battery and Diffusion  Performance of Li+ in the Materials

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (4): 946.

• Articles • Previous Articles Next Articles

Preparation of LiNi0.5Mn1.5O4 as 5 V Cathode Materials for Lithium Ion Battery and Diffusion Performance of Li+ in the Materials

LU Hua-Quan, WU Feng, SU Yue-Feng*, LI Ning, CHEN Shi, BAO Li-Ying

School of Chemical Engineering & Environment, Beijing Institute of Technology, National Development Center of Hi-Tech Green Materials, Beijing 100081, China

Received:2010-06-21 Revised:2010-10-19 Online:2011-04-10 Published:2011-03-09
Contact: SU Yue-Feng E-mail:suyuefeng@bit.edu.cn
Supported by:
国家“九七三”计划项目(批准号: 2009CB220100)资助.

Abstract

Abstract: 5 V cathode material LiNi0.5M1.5O4 was synthesized via an oxalate co-precipitation method, and the relationship between the structure, morphology and the electrochemical performance of the material were investigated. The results show that the sample synthesized at 900 ℃ has the best electrochemical performance, and its reversible capacity reaches 133.0 mAh?g-1. After 30 cycles, this LiNi0.5Mn1.5O4 sample maintains a discharge capacity of 132.2 mAh?g-1 with a capacity retention rate of 99.4%. The chemical diffusion coefficient of Li-ion in LiNi0.5M1.5O4 cathode material was measured by potentiostatic intermittent titration technique (PITT). It’s found that at the different voltage point of the discharge process, the change of Li content and the redox couple is also different, thus the chemical diffusion coefficient of Li-ion is various, it ranges in 10e-10 cm2?s-1~10e-11 cm2?s-1.

Key words: Lithium-ion batteries, Cathode material, Oxalate co-precipitation； LiNi0.5Mn1.5O4； Diffusion coefficient

TrendMD:

LU Hua-Quan, WU Feng, SU Yue-Feng*, LI Ning, CHEN Shi, BAO Li-Ying. Preparation of LiNi0.5Mn1.5O4 as 5 V Cathode Materials for Lithium Ion Battery and Diffusion Performance of Li+ in the Materials[J]. Chem. J. Chinese Universities, 2011, 32(4): 946.

References

Related Articles 15

[1]	ZHANG Shiyu, HE Runhe, LI Yongbing, WEI Shijun, ZHANG Xingxiang. Fabrication of Lithium-sulfur Battery Cathode with Radiation Crosslinked Low Molecular Weight of Polyacrylonitrile and the Mechanism of Sulfur Storage [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210632.
[2]	BAO Junquan, ZHENG Shibing, YUAN Xuming, SHI Jinqiang, SUN Tianjiang, LIANG Jing. An Organic Salt PTO（KPD）₂ with Enhanced Performance as a Cathode Material in Lithium-ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(9): 2911.
[3]	GAO Xiaole, WANG Jiaxin, LI Zhifang, LI Yanchun, YANG Donghua. Synthesis of NiO_x-ZSM-5 Composite Materials and Its Electrocatalytic Hydrogen Evolution Performance in Microbial Electrolysis Cell [J]. Chem. J. Chinese Universities, 2021, 42(9): 2886.
[4]	WANG Yimeng, LIU Kai, WANG Baoguo. Coating Strategies of Ni-rich Layered Cathode in LIBs [J]. Chem. J. Chinese Universities, 2021, 42(5): 1514.
[5]	ZHANG Huishuang, GAO Yanxiao, WANG Qiuxian, LI Xiangnan, LIU Wenfeng, YANG Shuting. High-low Temperature Properties of Ni-rich LiNi_0.6Co_0.2Mn_0.2O₂ Cathode Material by Hydrothermal Synthesis with CTAB Assisted [J]. Chem. J. Chinese Universities, 2021, 42(3): 819.
[6]	LU Di,ZHENG Chunman,CHEN Yufang,LI Yujie,ZHANG Hongmei. Synthesis of Li-rich Layers/Spinel/Carbon Composite Cathode Materials with Phenol Formaldehyde Resin and Its Electrochemical Performance^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1684.
[7]	LI Xin, CHEN Liang, MA Xiaotao, ZHANG Ding, XU Shoudong, ZHOU Xianxian, DUAN Donghong, LIU Shibin. Preparation of V₂O₃ Hollow Spheres for Lithium Sulfur Batteries ^† [J]. Chem. J. Chinese Universities, 2019, 40(9): 1972.
[8]	YAO Fengnan,LI Yu,FENG Wei. Synthesis and Electrochemical Performance of Carbon-coated FeF₂ Nanocomposite^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1418.
[9]	YANG Jinge, LI Yujie, LU Di, CHEN Yufang, SUN Weiwei, ZHENG Chunman. Morphology Control and Lithium Storage Performance of Micro/nano Li-rich Cathode Material^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1495.
[10]	MA Dongwei,TIAN Runsai,LIU Zhenjiang,FENG Yuanyuan,DING Hongyu,FENG Jijun. Microwave-assisted Synthesis and Electrochemical Performance of Na-Doped Cathode Materials Li_2-_xNa_xMnSiO₄/C^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1280.
[11]	CHEN Hong,DU Yonghui,ZHANG Xin,LIU Wenyan,ZHOU Xiaoming. Preparation and Electrochemical Properties of Poly(3-hexylthiophene)-coated Lithium-rich Layered Cathode Material Li_1.18Ni_0.15Co_0.15Mn_0.52 $O 2 †$ [J]. Chem. J. Chinese Universities, 2019, 40(4): 777.
[12]	Jian LIU,Haihui DU,Tianjiang SUN,Qingshun NIAN,Haixia LI,Zhanliang TAO. Preparation and Electrochemical Properties of Calcium Bronze/Carbon Nanotubes Composites ^† [J]. Chem. J. Chinese Universities, 2019, 40(12): 2526.
[13]	LUO Man, JIANG Wenquan, HAN Xue, GUO Ronggui, LI Tao, YU Limin. Synthesis and Characterization of Full Concentration-gradient LiNi_0.643Co_0.055Mn_0.302O₂ Cathode Material for Lithium-ion Batteries [J]. Chem. J. Chinese Universities, 2018, 39(1): 148.
[14]	WANG Kun, HUANG Mengyi, ZHANG Xiaosong, HUANG Junjie, DENG Xiang, LIU Changlu. Preparation and Electrochemical Performance of LiNi_1/3Co_1/3Mn_1/3O₂@C Composite^† [J]. Chem. J. Chinese Universities, 2018, 39(1): 141.
[15]	ZHANG Dong, LI Tingting, QIU Hailong, WEI Yingjin, WANG Chunzhong, CHEN Gang, YUE Huijuan. Preparation and Characterization of N-doped Li₂FeSiO₄/C Cathode Materials for Lithium Ion Batteries [J]. Chem. J. Chinese Universities, 2017, 38(9): 1633.

Preparation of LiNi0.5Mn1.5O4 as 5 V Cathode Materials for Lithium Ion Battery and Diffusion Performance of Li+ in the Materials

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments