Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (3): 515.
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XUE Ming, LI Yang-Xue, HUANG Lin, QIU Shi-Lun*
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Abstract: Two metal-organic coordination polymers [M6(TDC)6(hmt)2(DMF)6(H2O)3 ? (H2O)] (JUC-85a and JUC-85b) (M = Cd or Mn, TDC = Thiophene-2,5-dicarboxylic, hmt = hexamethylenetetramine, DMF = N,N’-dimethylformamide and JUC = Jilin University China) have been synthesized by self-assembly of mixed ligands and corresponding transition metal salts under mild conditions, and characterized by single-crystal X-ray diffraction, elements analysis, TGA, topology analysis, PXRD and photoluminescent. X-ray crystallography reveals that JUC-85a and JUC-85b exhibit the same three-dimensional structure with a rare “loh1” type of (3,6)-connected networks. In addition, photoluminescent of JUC-85a has been characterized.
Key words: Metal-Organic Coordination polymer, Thiophene-2,5-dicarboxylic, (3,6)-connected networks
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XUE Ming, LI Yang-Xue, HUANG Lin, QIU Shi-Lun*. Synthesis, Structure and Characterization of Novel 3D Metal-organic Coordination Polymers: [M6(TDC)6(hmt)2(DMF)6(H2O)3·(H2O)](M=Cd, Mn)[J]. Chem. J. Chinese Universities, 2011, 32(3): 515.
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http://www.cjcu.jlu.edu.cn/EN/Y2011/V32/I3/515
