Diverse Structures of Two Zn(Ⅱ) Coordination Polymers with 5-Amino-tetrazolate and 1,4-Benzenedicarboxylate Tuned by Solvent System

doi:10.7503/cjcu20130716

Abstract

Abstract:

The hydrothermal reaction of 5-amino-tetrazole(HATz) and 1,4-benzenedicarboxylic acid(H₂BDC) with Zn(NO₃)₂ gave a new coordination polymer {[Zn₂(ATz)₂(BDC)(H₂O)₂] ·H₂O}_n(1), and when this reaction was carried out under N,N'-dimethylformamide(DMF) solvothermal condition, another new coordination polymer {[Zn₂(ATz)₂(BDC)(DMF)₂] }_n(2) was obtained. Complexes 1 and 2 were characterized by elemental analyses, infrared spectroscopy, single-crystal X-ray diffraction, and powder X-ray diffraction. Complex 1 exhibits a 2D 3-connected(6,3) honeycomb(hcb) network with the Zn(Ⅱ) ions as 3-connected nodes, and the μ₂-ATz^- and μ₂-BDC^2- ligands as linkers, and then strong hydrogen bonding interactions extend the 2D layers into 3D supramolecular framework. While, complex 2 possesses a 3D 6-connected primitive cubic(pcu) metal-organic framework with the binuclear Zn(Ⅱ) units [Zn₂(CO)₂] as 6-connected nodes, and the μ₂-ATz^- and μ₄-BDC^2- ligands as linkers. Furthermore, their thermal stabilities and photoluminescence at room temperature in solid state were also investigated.

Key words: Metal-organic coordination polymer, 5-Amino-tetrazole, 1,4-Benzenedicarboxylic acid, Fluorescence property

CLC Number:

O614

TrendMD:

LU Wen-Guan, LIU Hong-Wen, YIN Xu-Guang, LAN Lu-Mei, LIU Hai-Yao. Diverse Structures of Two Zn(Ⅱ) Coordination Polymers with 5-Amino-tetrazolate and 1,4-Benzenedicarboxylate Tuned by Solvent System[J]. Chem. J. Chinese Universities, 2013, 34(12): 2691.

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