Synthesis and Properties of Sulfonated Poly(phthalazinone ether ketone) Ionomers Containing Poly(fluorene ether ketone) Hydrophobic Moieties

Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (10): 2074.

• Articles • Previous Articles Next Articles

Synthesis and Properties of Sulfonated Poly(phthalazinone ether ketone) Ionomers Containing Poly(fluorene ether ketone) Hydrophobic Moieties

LI Xiu-Hua*, XIAO Dai-Li

School of Chemistry & Chemical Engineering, South China University of Technology, Guangzhou 510641,China

Received:2010-01-04 Online:2010-10-10 Published:2010-10-10
Contact: LI Xiu-Hua. E-mail: lixiuhua@scut.edu.cn
Supported by:
教育部高等学校博士学科点基金(批准号: x2hgC7080170)和华南理工大学中央高校基本科研业务经费(批准号: 2009ZM0094)资助.

Abstract

Abstract: A series of sulfonated poly(phthalazinone ether ketone) ionomers containing poly(fluorene ether ketone) hydrophobic moieties as the polymer electrolytes for fuel cell appliaction were synthesized. To obtain multiblock poly(phthalazinone ether ketone) ionomers, one-pot two step nucleophilic polycondensation was run. Ionomers with various IEC were synthesized by adjusting the molar ratios and feeding sequence of fluorene bisphenol, bisphthalazinone monomer, sulfonated difluoro benzophenone, and difluoro benzophenone. The so-made polymers have high molecular mass, good thermal stabilities, oxidation resistance and hydrolysis resistance, moderate water-uptakes. They demonstrate good alcohol resistance at refluxing temperature and proton conductivity and can be potentially used as proton exchange membranes for fuel cells.

Key words: Fluorene bisphenol, Poly(phthalazinone ether ketone), Sulfonation, Polycondensation, Ionomer

TrendMD:

LI Xiu-Hua*, XIAO Dai-Li. Synthesis and Properties of Sulfonated Poly(phthalazinone ether ketone) Ionomers Containing Poly(fluorene ether ketone) Hydrophobic Moieties[J]. Chem. J. Chinese Universities, 2010, 31(10): 2074.

References

[1]Rikukawa M., Sanui K.. Prog. Polym. Sci.[J], 2000, 25(10): 1463—1502 [2]Kreuer K. D.. J. Membr. Sci.[J], 2001, 185: 29—39 [3]Smitha B., Sridhar S., Khan A. A.. J. Membr. Sci.[J], 2005, 259: 10—26 [4]Zhao C., Li X., Wang Z., Dou Z., Zhong S., Na H.. J. Membr. Sci.[J], 2006, 280: 643—650 [5]Wang L., Meng Y. Z., Wang S. J., Li X. H., Xiao M.. J. Polym. Sci., Part A: Polym. Chem.[J], 2005, 43: 6411—6418 [6]Wang L., Meng Y. Z., Wang S. J., Li X. H., Xiao M., Wang S. J., Hay A. S.. J. Membr. Sci.[J], 2006, 280: 108—115 [7]WANG Lei(王雷), MENG Yue-Zhong(孟跃中), WANG Shuan-Jin(王拴紧), ZHU Guang-Ming(朱光明). Chem. J. Chinese Universities(高等学校化学学报)[J], 2007, 28(7): 1408—1410 [8]Chen Y. L., Meng Y. Z., Li X. H., Hay A. S.. Macromolecules[J], 2005, 38: 10007—10013 [9]Chen Y. L., Meng Y. Z., Wang S. J., Tian S. H., Hay A. S.. Macromol. Chem. Phys.[J], 2006, 207: 653—659 [10]PAN Hai-Yan(潘海燕), LIANG Yong-Fang(梁勇芳), ZHU Xiu-Ling(朱秀玲), ZHANG Shou-Hai(张守海), JIAN Xi-Gao(蹇锡高). Chem. J. Chinese Universities(高等学校化学学报)[J], 2007, 28(1): 173—176 [11]Chen Y. L., Meng Y. Z., Wang S. J., Tian S. H., Chen Y., Hay A. S.. J. Membr. Sci.[J], 2006, 280: 433—411 [12]Shang X., Li X., Xiao M., Meng Y.. Polymer[J], 2006, 47: 3807—3813 [13]Ding F. C., Wang S. J., Xiao M., Li X. H., Meng Y. Z.. J. Power Sources[J], 2007, 170: 20—27 [14]Yang Y., Shi Z., Holdcroft S.. Macromolecules[J], 2004, 37: 1678—1681 [15]Genies C., Mercier R., Sillion B., Petiaud R., Cornet N., Gebel G., Pineri M.. Polymer[J], 2001, 42: 5097—5105 [16]Yang Y., Holdcroft S.. Fuel Cells[J], 2005, 5: 171—186 [17]Tian S. H., Meng Y. Z., Hay A. S.. Macromolecules[J], 2009, 42(4): 1153—1160 [18]Wang S. J., Meng Y. Z., Tjong S. C., Hlil A. R., Hay A. S.. J. Polym. Sci., Part A: Polym. Chem.[J], 2003, 41: 2481—2490

Synthesis and Properties of Sulfonated Poly(phthalazinone ether ketone) Ionomers Containing Poly(fluorene ether ketone) Hydrophobic Moieties

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	FU Zhinan, TAN Yunlong, XIAO Guyu, YAN Deyue. Synthesis and Properties of Sulfonated Poly（phthalazinone ether phosphine oxide）s with Perfluorobiphenyl Moieties for Proton Exchange Membranes [J]. Chem. J. Chinese Universities, 2021, 42(8): 2635.
[2]	ZHANG Jun, WANG Bin, PAN Li, MA Zhe, LI Yuesheng. Synthesis and Properties of Imidazolium-based Polyethylene Ionomer [J]. Chem. J. Chinese Universities, 2020, 41(9): 2070.
[3]	CHENG Qinwen, YUAN Bo, ZHU Xiangdong, ZHANG Kai, ZHANG Xingdong. Surface Elemental Compositions and in Vitro Bioactivities of the PEEK Materials with Various Sulfonation and Alkali Treatments [J]. Chem. J. Chinese Universities, 2019, 40(8): 1757.
[4]	DONG Xiangyang,NIU Xiaoqing,WEI Jishi,XIONG Huanming. One-step Hydrothermal Synthesis of Copper Doped Carbon Dots and Their Application in White Light Devices^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1288.
[5]	XIAO Lei, ZHANG Chen, HE Meiyu, CHEN Kangcheng. Precise Controllable Post-sulfonation for Preparation of Sulfonated Poly(arylene ether sulfone)s and Their Properties for Proton Exchange Membrane^† [J]. Chem. J. Chinese Universities, 2018, 39(6): 1281.
[6]	WANG Peng, WU Xian, ZHANG Hanyu, YOU Kaiyuan, LIU Zhenchao, LIU Baijun. Preparation of the Blend Membranes Based on Sulfonated Polyetheretherketoneketone and Amine-terminated Hyperbranched Polyimide^† [J]. Chem. J. Chinese Universities, 2018, 39(3): 405.
[7]	LIANG Yu, CHEN Zhihao, LIANG Baoyan, HU Zhe, YANG Xiaomin, WANG Zichen. Preparation of Rice Husk Carbon-based Solid Acid Catalyst for the Dehydration of Xylose to Furfural^† [J]. Chem. J. Chinese Universities, 2016, 37(6): 1123.
[8]	LU Miao, LIU Jianyun, WANG Shiping, CHENG Jian. Preparation of Sulfonated Graphene/Activated Carbon Composite Electrode for Asymmetric Capacitive Deionization^† [J]. Chem. J. Chinese Universities, 2014, 35(7): 1546.
[9]	LI Yongqiang, SONG Yongcai. Synthesis and Spinnability of the High Softening-point Polycarbosilane^† [J]. Chem. J. Chinese Universities, 2014, 35(10): 2272.
[10]	ZHANG Shou-Hai, JIANG Yi-Wen, CHEN Li-Yun, JIAN Xi-Gao. Synthesis and Properties of Sulfonated Poly(phthalazinone ether ketone ketone)s Containing Pendant Phenyl Groups [J]. Chem. J. Chinese Universities, 2013, 34(8): 1993.
[11]	ZHAO Jing, XU Hong-Jie, FANG Jian-Hua, YIN Jie. Synthesis and Characterization of Sulfonated Polyamides [J]. Chem. J. Chinese Universities, 2012, 33(05): 1106.
[12]	CHEN Yong, WANG Shuan-Jin, XIAO Min, MENG Yue-Zhong. Synthesis and Characterization of Novel Sulfonated Poly(arylene ether nitrile ketone)s Containing Dicyanoarylene Group [J]. Chem. J. Chinese Universities, 2007, 28(2): 362.
[13]	DOU Zhi-Yu, LIU Chen-Guang,LI Xian-Feng,ZHAO Cheng-Ji, ZHONG Shuang-Ling, NA Hui. Synthesis and Characterization of a Novel Sulfonated Polyimide Used as Proton Exchange Membrane [J]. Chem. J. Chinese Universities, 2006, 27(3): 586.
[14]	QIAO Qian, HAN Yi-Jun, CHEN Yan-Mo, LIU Gui-Yun, ZHAOYa-Juan, LIU Ruo-Wang. Studies on Polycondensation of BHEN [J]. Chem. J. Chinese Universities, 2006, 27(2): 386.
[15]	LIU Cheng, LIU Peng-Tao, WANG Jin-Yan, WU Chun-Rui, WANG Pei, JIAN Xi-Gao . Synthesis, Characterization and Properties of New Soluble Phthalazinone Moiety-based Aromatic Poly(aryl amide)s Containing Chlorine Substituents [J]. Chem. J. Chinese Universities, 2005, 26(3): 558.