Preparation and Bactericidal Activity of C12A7-O- Nanoparticles

Abstract

Abstract: C12A7-O-{[Ca24Al28O64]4+·4(O-)} nanoparticles were prepared by sol-gel method. The synthesized C12A7-O- nonaparticles were investigated by X-ray diffraction, electron spin resonance and transmission electron microscopy. The antibacterial test of the C12A7-O- nonaparticles was also performed against E. coli(DH5α), S. aureus(ATCC 6538) and B. subtilis(ATCC 9372). The results show that the best condition for preparing C12A7-O- nanoparticles was sintering at 1150 ℃ for 6 h in oxygen ambience. The mean particle size of the C12A7-O- nanoparticles was 74 nm, and the cell parameter of the C12A7(Ca12Al14O33)cage with a O-concentration of 1.2×1020 cm-3 was (1.199±0.004) nm. The C12A7-O- nanoparticles also exhibited excellent broad-spectrum antibacterial activity. The unique features of present material such as thermal stability, environment-friendly property and safety, could be potentially utilized in antibacterial materials.

Key words: C12A7-O- nanoparticle, Sol-gel method, Bactericidal activity

TrendMD:

GONG Lu, SHEN Jing, LI Quan-Xin*. Preparation and Bactericidal Activity of C12A7-O- Nanoparticles[J]. Chem. J. Chinese Universities, 2010, 31(10): 1919.

References

[1]LIU Qing-Ju(柳清菊), WANG Yu-De(王毓德), ZHAO Jing-Chang(赵景畅), XIANG Jin-Zhong(项金钟), WU Xing-Hui(吴兴惠). J. Inorg. Mater.(无机材料学报)[J], 2002, 17(1): 73—78 [2]CAI Xiao-Hui(蔡晓慧), ZHU Guang-Shan(朱广山), GAO Bo(高波), ZHANG Wei-Wei(张维维), ZHANG Da-Liang(张大梁), WEI Yu-Hong(魏玉红), QIU Shi-Lun(裘式纶), WANG Ce(王策). Chem. J. Chinese Universities(高等学校化学学报)[J], 2006, 27(11): 2042—2044 [3]Hayashi K., Hirano M., Matsuishi S., Hosono H.. J. Am. Chem. Soc.[J], 2002, 124(5): 738—739 [4]Li Q. X., Hayashi K., Nishioka M., Kashiwagi H., Hirano M., Torimoto Y., Hosono H., Sadakata M.. Appl. Phys. Lett.[J], 2002, 80(22): 4259—4261 [5]Li Q. X., Nishioka M., Kashiwagi H., Sadakata M., Hosono H., Hirano M., Hayashi K., Torimoto Y.. Surf. Sci.[J], 2003, 527(1—3): 100—112 [6]Li J., Huang F., Wang L., Wang Z. X., Yu S. Q., Torimoto Y., Sadakata M., Li Q. X.. J. Phys. Chem. B[J], 2005, 109(30): 14599—14603 [7]Li J., Huang F., Wang L., Yu S. Q., Torimoto Y., Sadakata M., Li Q. X.. Chem. Mater.[J], 2005, 17(10): 2771—2774 [8]Huang F., Li J., Wang L., Dong T., Tu J., Torimoto Y., Sadakata M., Li Q. X.. J. Phys. Chem. B[J], 2005, 109(24): 12032—12037 [9]Huang F., Li J., Xian H., Tu J., Sun J. Q., Yu S. Q., Li Q. X., Torimoto Y., Sadakata M.. Appl. Phys. Lett.[J], 2005, 86(11): 114101 [10]Song C. F., Sun J. Q., Li J., Ning S., Yamamoto M., Tu J., Torimoto Y., Li Q. X.. J. Phys. Chem. C[J], 2008, 112(48): 19061—19068 [11]Song C. F., Sun J. Q., Qiu S. B., Yuan L. X., Tu J., Torimoto Y., Sadakata M., Li Q. X.. Chem. Mater.[J], 2008, 20(10): 3473—3479 [12]Sun J. Q., Song C. F., Ning S., Lin S. B., Li Q. X.. Acta Phys. Chim. Sin.[J], 2009, 25(9): 1713—1720 [13]Sun J. Q., Song C. F., Ning S., Lin S. B., Li Q. X.. Chin. J. Chem. Phys.[J], 2009, 22(4): 417—422 [14]Wang L., Gong L., Zhao E, Yu Z., Torimoto Y., Sadakata M., Li Q. X.. Lett. Appl. Microbiol.[J], 2007, 45(2): 200—205 [15]Wang L., Yan L. F., Zhao P. T., Torimoto Y., Sadakata M., Li Q. X.. Appl. Surf. Sci.[J], 2008, 254(13): 4191—4200 [16]Palacios L., De La Torre A. G., Bruque S., Garcia-Munoz J. L., Garcia-Granda S., Sheptyakov D., Aranda M. A. G.. Inorg. Chem.[J], 2007, 46(10): 4167—4176 [17]Vincent M. G., Jeffery J. W.. Acta Crystallogr., Sect. B[J], 1978, 34(5): 1422—1428 [18]Zhmoidin G. I., Chatterjee A. K.. Cem. Concr. Res.[J], 1984, 14(3): 386—396 [19]Mondal P., Jeffery J. W.. Acta Crystallogr., Sect. B[J], 1975, 31(3): 689—697 [20]Jeevaratnam J., Glasser F. P., Glasser Dent L. S.. J. Am. Ceram. Soc.[J], 1964, 47(2): 105—106 [21]Hayashi K., Matsuishi S., Ueda N., Hirano M., Hosono H.. Chem. Mater.[J], 2003, 15(9): 1851—1854

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