Studies on the Kinetics of Thermal Oxidation of Rosin and Abietic Acid on the Polyethylene Film

Abstract

Abstract:

The kinetics of thermal oxidation of rosin and abietic acid absorbed on the polyethylene film were respectively studied. The kinetic equation of heat oxidation was determined by UV spectrophotometry. The experimental results show that the thermal oxidation reaction of both rosin and abietic acid are pseudo first order reaction. When the reaction temperatures were 303.15, 308.15, 313.15, 318.15, 323.15 and 328.15 K, respectively, the apparent reaction rate constants of abietic acid were 0.0036, 0.0041, 0.0062, 0.0087, 0.011 and 0.0157 min^-1, respectively. Its reaction activation energy was 50.29 kJ/mol. when the reaction temperatures were 308.15, 313.15 and 318.15 K, respectively, the apparent reaction rate constants of rosin were 0.0009, 0.0015 and 0.0025 min^-1. The reaction activation energy was 80.2 kJ/mol.

Key words: Rosin, Abietic acid, Oxidation reaction, Kinetics, Rate constant

TrendMD:

QIN Rong-Xiu, HUANG Pin-Xian, LIU Xiong-Min*, MA Li, WU Yan-Ling. Studies on the Kinetics of Thermal Oxidation of Rosin and Abietic Acid on the Polyethylene Film[J]. Chem. J. Chinese Universities, 2009, 30(5): 954.

References

Lin C. H., Chuang H. S.. Use of Abietic Acid and Derivatives There of for Inhibiting Cancer, US 7015248[P], 2006
Imamura P. M., Dos S. C.. Synth. Commun.[J], 2005, 35(15): 2057—2065
Khlebnikova T. B., Karpyshev N. N., Tolstikova V., et al.. Chirality[J], 2004, 16: S40—S50
Gigante B., Santos C., Silva A. M., et al.. Bioorganic and Medicinal Chemistry[J], 2003, 11(8): 1631—1638
Alvarez E. J., Chahboun R., Guardia J. J., et al.. Tetrahedron Letters[J], 2006, 47(15): 2577—2580
Alvarez E. J., Chahboun R., Bentaleb F., et al.. Synlett.[J], 2004, 15: 2701—2704
Presser A., Potschger I., Hasllnger E., et al.. Monatshefte Fur Chemie[J], 2002, 33: 231—239
Koichi M., Takeshi I., Hirokazu N., et al.. Biotechnology Letters[J], 2005, 27(17): 1305—1310
Takahashia N., Kawadaa T., Gotoa T., et al.. Febs Letters[J], 2003, 550: 190—194
ZHONG Guo-Hua(钟国华). Guangxi Forestry Science(广西林业科学)[J], 1997, 26(2): 77—79
Paul F., Ritchie, Lane F.. Mcburne. J. Am. Chem. Soc.[J], 1950, 72: 1197—1200
Virginla M. L., Doris E. B., O′Conno R. T.. J. Am. Chem. Soc.[J], 1955, 77: 6311—6313
Virginia M. L., Ray V. L.. J. Am. Chem. Soc.[J], 1958, 79: 1497—1499
Hiroshi T., Warter H. S., Ray V. R.. J. Am. Chem. Soc.[J], 1968, 3(4): 1683—1684
YE Kai-Rong(叶恺荣), JIANG Jia-Jun(蒋家俊), FENG Ke(冯克). Journal of Fujian Teachers University(福建师范大学学报)[J], 1989, 5(3): 69—75
Malevskaya S. S., Kazeeva E. V.. Zhurnal Prikladnoi Khimii.[J], 1948, 21: 854—858
WANG Tao(王涛), SU Zi-An(粟子安). Chemistry and Industry of Forest Products(林产化学与工业)[J], 1991, 11(3): 173—181
Enoki A., Kitao K. J.. Jap. Wood Res. Soc.[J], 1975, 21(I 2): 101—106
Harris G. C.. Sanderson T. F.. Org. Synth.[J], 1952, 32: 1—4
Moor R. N., Lawrence R. V. L.. J. Am. Chem. Soc.[J], 1958, 80: 1438—1440
Moor R. N., Lawrence R. V. L.. J. Am. Chem. Soc.[J], 1960, 82: 1734—1738
Moor R. N., Lawrence R. V. L.. J. Am. Chem. Soc.[J], 1961, 83: 2563—2570
SU Zi-An(粟子安), YU Qi-Zhuang(虞启庄), GUO Chang-Tai(郭长泰), et al.. Forest Product Chemistry Chemical Industry Academic Society Academic Conference Collection(中国林学会林产化学化工学会学术会议论文集)[C], Nanjing, 1986: 40—55
Harris G. C., Sanderson T. F.. J. Am. Chem. Soc.[J], 1948, 70: 334—339

[1]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[2]	YANG Lijun, YU Yang, ZHANG Lei. Construction of Dual-functional 2D/3D Hydrid Co₂P-CeO _x Heterostructure Integrated Electrode for Electrocatalytic Urea Oxidation Assisted Hydrogen Production [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220082.
[3]	SUN Cuihong, LYU Liqiang, LIU Ying, WANG Yan, YANG Jing, ZHANG Shaowen. Mechanism and Kinetics on the Reaction of Isopropyl Nitrate with Cl， OH and NO₃ Radicals [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210591.
[4]	WANG Jian, ZHANG Hongxing. Theoretical Study on the Structural-photophysical Relationships of Tetra-Pt Phosphorescent Emitters [J]. Chem. J. Chinese Universities, 2021, 42(7): 2245.
[5]	MA Zihui, WANG Mengyan, CAO Hongyu, TANG Qian, WANG Lihao, ZHENG Xuefang. Transient Absorption and Decay Kinetic Properties of Photo-excited Metal Coordinated Tetraphenylporphyrin [J]. Chem. J. Chinese Universities, 2021, 42(3): 767.
[6]	SHUAI Die, ZHAO Meijuan, CHEN Bingnian, WANG Li. Inhibitory Effect of Four Kinds of Keegin-type Phosphomolybdate on Tyrosinase and Melanin Formation and Its Antioxidant Activities [J]. Chem. J. Chinese Universities, 2021, 42(12): 3579.
[7]	ZHANG Aiqin, WANG Man, SHEN Gangyi, JIN Jun. Interactions Between Polybrominated Diphenyl Ethers and Human Serum Albumin Using SPR and Molecular Docking [J]. Chem. J. Chinese Universities, 2020, 41(9): 2054.
[8]	ZHOU Hua, LI Zhenhua, KONG Xianggui, DUAN Haohong. Recent Progress in Electrochemical Catalytic Conversion of Biomass Platform Molecules into High-value Added Fuels and Chemicals^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1449.
[9]	LI Xiangyuan,YAO Xiaoxia,SHENTU Jiangtao,SUN Xiaohui,LI Juanqin,LIU Mingxia,XU Shimin. Combustion Reaction Mechanism Construction by Two-parameter Rate Constant Method ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 512.
[10]	WANG Lianping,LI Qingjie,LIU Xiaoyan,REN Yueying,YANG Xiuwei. Screening of Cholinesterase Inhibitors in Fructus Evodiae Alkaloids Based on UFLC-MS/molecular Simulation ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 111.
[11]	ZHANG Chenglu,GONG Rongqing,YANG Jingyi,SUN Xiaona,LI Yilin,WANG Huayu,SONG Fulu,SUN Yuedong. Synthesis of Novel Polyheterocyclic Molecules with 1,3,4-Oxadiazole Thioetheramide as Core Framework and Their Inhibitory Activity on Cdc25B and PTP1B^† [J]. Chem. J. Chinese Universities, 2019, 40(2): 262.
[12]	SUN Guangdong, PAN Xiaopeng, ZHONG Yuhao, CHEN Enyu, HUANG Yi, SHAO Jianzhong. Photopolymerization Kinetics of Poly(Acrylate Acid) Hydrogels Induced by Blue Light ^† [J]. Chem. J. Chinese Universities, 2019, 40(11): 2404.
[13]	XIAO Biyuan,QIU Jiangyuan,QIN Fanghong,WAN Ting,XU Yaqun,NONG Xiaohui,HUANG Zaiyin. Study on Particle Size Effect on Adsorption Thermodynamics and Kinetics of Cubic Nano-Cu₂O ^† [J]. Chem. J. Chinese Universities, 2019, 40(10): 2214.
[14]	SHI Weiguang,QING Hongxia,ZHANG Shangshang,LU Xiaoyi,WANG Xiaofeng,LI Benxian,XU Xiaohu,LIU Weiguo,WANG Jun,DONG Zhaohui. Kinetics and Abnormal Inhibition of THF on Ethylene Hydrate Formation from Ice Powder Based on Conversion Rate^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1968.
[15]	WANG Ning,ZHU Huifang,WANG Lu,ZHANG Tiantian,GU Jiali,SHU Jie. Structural Identification and Asymmetric-exchange Dynamics Study of Esomeprazole Magnesium in Specific Solution as Probed by Using ¹H NMR Spectra^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1919.