Synthesis and Properties of Poly(aryl ether ketone) Macrocyclic Oligomer with Electroactive Groups

Chem. J. Chinese Universities

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Synthesis and Properties of Poly(aryl ether ketone) Macrocyclic Oligomer with Electroactive Groups

YANG Li-Guo, YAO Lei, WANG Yong-Guo, BEN Teng*, ZHANG Wan-Jin

Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China

Received:2007-12-03 Revised:1900-01-01 Online:2008-03-10 Published:2008-03-10
Contact: BEN Teng

Abstract

Abstract: A new electroactive poly(aryl ether ketone) macrocyclic oligmer with phenyl-capped tetramer was synthesized by the modified pseudo-high-dilution method, whose structure with a rigid molecular backbone contains a cavity of well-defined size. The oligomer was characterized with mass spectrometry, IR and ¹H NMR, ¹³C NMR spectroscopies. Its redox property was checked by cyclic voltammetry and chemical oxidation process was monitored by UV spectroscopy. We found that it has a reversible electrochemical property like common oligoanilines. Combined with its well-defined structure, the oligmer is expected to act as a kind of host molecules which are capable of molecular recognition.

Key words: Electroactivity, Macrocyclic oligomer, Oligoanilines, Poly(aryl ether ketone)

CLC Number:

O631

TrendMD:

YANG Li-Guo, YAO Lei, WANG Yong-Guo, BEN Teng*, ZHANG Wan-Jin. Synthesis and Properties of Poly(aryl ether ketone) Macrocyclic Oligomer with Electroactive Groups[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Properties of Poly(aryl ether ketone) Macrocyclic Oligomer with Electroactive Groups

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