CJCU

Chem. J. Chinese Universities

• 研究论文 • Previous Articles     Next Articles

Synthesis and Characterization of a Novel Trifunctional Cycloaliphatic Epoxide Resin and Its Photosensivity of Cationic Photopolymerization

ZHANG Zhi-Sen;ZHANG Xiao-Hua;XU Wei-Jian*;XIONG Yuan-Qin; ZHANG Zheng-Hua; XIA Xin-Nian   

  1. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
  • Received:2005-09-01 Revised:1900-01-01 Online:2006-07-10 Published:2006-07-10
  • Contact: XU Wei-Jian

PDF (PC)

Cited

6

Abstract:

Started from dicyclopentadiene, a novel, liquid, trifunctional cycloaliphatic epoxide resin was synthesized and characterized. The photosensitivity of cationic photopolymerization of the resulting epoxide initiated by photoinitiator(CH3-C6H5)2I+PF-6 was studied. Meanwhile, the promotion of organic peroxide on photopolymerization of the epoxide was discussed. The results show that BPO could promote the initiation of (CH3-C6H5)2I+PF-6 significantly. The cured film of the synthesized epoxide has an excellent heat stability.

Key words: Cycloaliphatic epoxide resin, Dicyclopentadiene, Cationic photopolymerization, Heat stability

CLC Number: 

TrendMD: