Nano-structural Characters of Highly Active and Stable Ni/ZrO2 Catalyst for CO2 Reforming of Methane

Abstract

Abstract: Ni/ZrO₂ catalysts with different phase compositions and crystal sizes of ZrO₂ nanoparticles were prepared and used to catalyze the methane reforming reaction with CO₂. Catalyst characterizations with XRF, XRD, TEM, TPR and H₂-TPD show that highly active and stable Ni/ZrO₂ catalysts are nanocomposites of comparably sized metallic Ni and ZrO₂ nanoparticles. The phase composition of ZrO₂ in the catalysts has little effect on the catalytic stability.

Key words: Nickel catalyst, Zirconia, Crystal phase composition, Nanocomposite catalyst, CO₂ reforming of CH₄

CLC Number:

O643.3

TrendMD:

LI Yan, WANG Yu-He, XU Bo-Qing. Nano-structural Characters of Highly Active and Stable Ni/ZrO₂ Catalyst for CO₂ Reforming of Methane[J]. Chem. J. Chinese Universities, 2005, 26(7): 1325.

References

[1] Bradfo rd M.C.J.,Vann ice M.A..Catal.Rev.Sc.iEng.[J],1999,41:1—26 [2] Lercher J.A.,Bitter J.H.,Hally W.et al..Stud.Su rf.Sci.Catal.[J],1996,101:463—472 [3] Tom ish ige K.,Yam azak i O.,Chen Y.G.et al..Catal.Today[J],1998,45:35—39 [4] Chen P.,Zhang H.B.,Lin G.D.et al..App l.Catal.A[J],1998,166:343—350 [5] Kim J.H.,Suh D.J.,Park T.J.et al..App l.Catal.A[J],2000,197(2):191—200 [6] J IMin(纪敏),W U Zh i-Yun(吴志芸),B I Ying-Li(毕颖丽)et al..J.Mo l.Catal.(分子催化)[J],1998,12(5):355—361 [7] XU Zheng(许峥),ZHAN G Liu(张鎏),ZHAN G Ji-Yan(张继炎).Ch in.J.Catal.(催化学报)[J],2001,22(1):18—22 [8] Chen Y.G.,Tom ish ige K.,Yokoyam a K.et al..App l.Catal.A[J],1997,165:335—347 [9] Yo rk A.P.E.,Claridge J.B.,Brung s A.J.et al..Chem.Comm un.[J],1997:39—40 [10] Rucken stein E.,Wang H.Y..J.Catal.[J],2002,205:289—293 [11] Nagaoka K.,Takanabe K.,Aika K.I..App l.Catal.A[J],2003,255:13—21 [12] Wei J.M.,Xu B.Q.,Li J.L.et al..App l.Catal.A[J],2000,196:L 167—L 172 [13] W E I Jun-Mei(魏俊梅),XU Bo-Qing(徐柏庆),L I Jin-Lu(李晋鲁)et al..Chem.J.Ch inese Un iversities(高等学校化学学报)[J],2002,23(1):92—97 [14] W E I Jun-Mei(魏俊梅),XU Bo-Qing(徐柏庆),SU N Ke-Qiang(孙科强)et al..Chem.J.Ch inese Un iversities(高等学校化学学报)[J],2002,23(11):2106—2111 [15] Xu B.Q.,Wei J.M.,Yu Y.T.et al..J.Phys.Chem.B[J],2003,107(22):5203—5207 [16] Xu B.Q.,Wei J.M.,Yu Y.T.et al..Top.Catal.[J],2003,22:77—85 [17] L I Yan(李艳),YE Qing(叶青),W E I Jun-Mei(魏俊梅)et al..Ch in.J.Catal.(催化学报)[J],2004,25(4):326—330 [18] Cen ti G.,Cerrato G.,Angelo S.D.et al..Catal.Today[J],1996,27:265—270 [19] Adeeva V.,Xu B.Q.,Sach tler W.M.H.et al..Top.Catal.[J],1998,6:61—76 [20] Tanabe K.,Misono M.,Ono Y.et al..New So lid Acid s and Bases[M],Tokyo-Am sterdam:Kodan sha-Elsevier,1989 [21] Kuba S.,Luk in skas P.,Grasselli R.K.et al..J.Catal.[J],2003,216:353—361 [22] Jung K.T.,Bell A.T..J.Mo l.Catal.A[J],2000,163:27—42 [23] He D.P.,Ding Y.J.,Li C.et al..J.Mo l.Catal.A[J],2004,208:267—271 [24] Mon toya J.A.,Rom ero-Pascual E.,Gim on C..Catal.Today[J],2000,63:71—85 [25] Stagg S.M.,Rom eo E.,Resasco D.E.et al..J.Catal.[J],1998,178:137—145 [26] No ronha F.B.,Fend ley E.C.,Resasco D.E.et al..Chem.Eng.J.[J],2001,82:21—31 [27] Xu B.Q.,Zhang Q.H.,Li Y..Proc.13th ICC[C],Paris,2004:4—167

Nano-structural Characters of Highly Active and Stable Ni/ZrO₂ Catalyst for CO₂ Reforming of Methane

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