Synthesis of Cyclic Carbonates Catalyzed by Ionic Liquid Mediated ZnBr2 Catalytic System

Abstract

Abstract: Ionic liquid mediated ZnBr₂ system could catalyze the chemical fixation of CO₂ with epoxides with a high selectivity(>98%) and TOF(5 580 h^-1) under mild reaction conditions and the catalyst could be reused five times almost without losing its catalytic activity and selectivity. Besides, the pure cis-cyclic carbonate of cyclohexene oxide was obtained over this catalyst system.

Key words: Chemical fixation of CO₂, cis-Cyclic carbonate, ZnBr² ionic liquid, Composite catalyst system

CLC Number:

O643

TrendMD:

LI Fu-Wei, XIAO Lin-Fei, XIA Chun-Gu. Synthesis of Cyclic Carbonates Catalyzed by Ionic Liquid Mediated ZnBr₂ Catalytic System[J]. Chem. J. Chinese Universities, 2005, 26(2): 343.

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Synthesis of Cyclic Carbonates Catalyzed by Ionic Liquid Mediated ZnBr₂ Catalytic System

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