Electrooxidation Study of 3-Picoline at PbO2-Solid Polymer Electrolyte Composite Electrode

Abstract

Abstract: The PbO₂-SPE(Solid Polymer Electrolyte) composite electrode was prepared by hot pressed method.The electrooxidation reactions of 3-picoline at the electrode was studied with the cyclic voltammetric and steady state polarization curves.The relationships between the current density and overpotential and between the overpotential and cell voltage were examined in the different catholyte as well as in the anolytes with or without the liquid supporting electrolyte.The possibility for producing nicotinic acid from 3-picoline at the(electrode) without the supporting electrolyte in the liquid phase was explored.The selectivity and the current (efficiency) under the specific conditions were given.

Key words: PbO₂-SPE composite electrode, 3-Picoline, Electrooxidation, Solid polymer electrolyte

CLC Number:

O646.5

TrendMD:

ZHANG Yu-Min, ZHANG Heng-Bin, XU Yu-Ling, CAO Xue-Jing, LIN Hai-Bo . Electrooxidation Study of 3-Picoline at PbO₂-Solid Polymer Electrolyte Composite Electrode[J]. Chem. J. Chinese Universities, 2005, 26(10): 1858.

[1]	YANG Yingjie, ZHANG Xiaorong, SUN Yuxue, LIU Jun, XIE Haiming. Synthesis of a Dual-lithium-salt Comb Polymer Electrolyte and Its Electrochemical Performance [J]. Chem. J. Chinese Universities, 2021, 42(9): 2861.
[2]	YU Yancun, WANG Xian, GE Junjie, LIU Changpeng, XING Wei. Promoted Formic Acid Electrooxidation Using PdN_x/C Catalyst Prepared with Hyperbranched Polymer^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1433.
[3]	FAN Zhongquan, CHEN Chen, SHEN Zhenlu, LI Meichao. One-pot Electrochemical Oxidation Synthesis of Nitriles from Alcohols with Hexamethyldisilazane as the Nitrogen Source^† [J]. Chem. J. Chinese Universities, 2018, 39(1): 78.
[4]	YAN Peng, ZHANG Dongming, CHENG Kui, XU Yang, LI Yingying, YE Ke, CAO Dianxue, WANG Guiling. Preparation of Pd-Ag/C@TiO₂ Core/shell Nanorods as Catalysts for Electrooxidation of NaBH₄^† [J]. Chem. J. Chinese Universities, 2015, 36(9): 1801.
[5]	SONG Yukun, LÜ Hong, HAO Chuanpu, MI Cangen. Effect of IrO₂ Modification of Ti Mesh on Electrochemical Performance of Collector Layer for Solid Polymer Electrolyte Electrolyzer^† [J]. Chem. J. Chinese Universities, 2015, 36(7): 1378.
[6]	LIU Yao, ZENG Ya-Chao, LIU Ran, WANG Gui-Ling, CAO Dian-Xue. Poisoning of Acetone to Electrooxidation of 2-Propanol at Pd Electrode [J]. Chem. J. Chinese Universities, 2012, 33(05): 1017.
[7]	CHEN Ming-Hui, HE Chun-Lan, ZHANG Bin-Wei, JIANG Yan-Xia, CHEN Sheng-Pei, SUN Shi-Gang. Electrooxidation of Formic Acid on Palladium Nanoparticles Supported on Ordered Mesoporous Carbon [J]. Chem. J. Chinese Universities, 2012, 33(02): 331.
[8]	WANG Gui-Ling1*, CHENG Yuan-Hui1, ZHANG Wei-Cai1, LU Tian-Hong2, CAO Dian-Xue1, . Electrocatalytic Performances of MmNi3.2Al0.2Mn0.6Co1.0 Modified with MnO2 for NaBH4 Oxidation [J]. Chem. J. Chinese Universities, 2010, 31(1): 153.
[9]	GAO Yang-Yan¹, LI Ke-Chang¹, GU Qiang¹, CHEN Xiao-Dong², ZHANG Heng-Bin¹, ZHANG Yu-Min^1*. Effect of Surfactants on the Electrooxidation of 3-Picoline to Nicotinic Acid [J]. Chem. J. Chinese Universities, 2009, 30(2): 365.
[10]	TIAN Mei*, YANG Li-Juan, CUI Rui-Hai, ZHANG Heng-Bin, BI Jing. Studies on Electrocatalytic Oxidation Mechanism of p-Methylphenol [J]. Chem. J. Chinese Universities, 2008, 29(7): 1420.
[11]	TIAN Mei^1*, YANG Li-Juan¹, CUI Rui-Hai¹, ZHANG Heng-Bin², HE Fang¹, LIU Yan-Chun¹. Electrooxidation of p-Methylphenol at Different Catalyst Electrodes [J]. Chem. J. Chinese Universities, 2008, 29(11): 2254.
[12]	LI Ke-Chang, CAO Xue-Jing, ZHANG Heng-Bin*, ZHANG Yu-Min. In-Cell Indirect Electrooxidation of 2-Picoline [J]. Chem. J. Chinese Universities, 2007, 28(9): 1747.
[13]	LI Fei, CAO Xue-Jing, ZHANG Heng-Bin, ZHANG Yu-Min, LI Ke-Chang. Electrooxidation of 2-Methylpyridine at PbO₂-SPE Composite Electrodes [J]. Chem. J. Chinese Universities, 2007, 28(1): 140.
[14]	XU Yu-Ling, CAO Xue-Jing, ZHANG Heng-Bin, ZHANG Yu-Min, LI Ke-Chang. Electrooxidation of 3-Picoline in Acetone/Water Mixed Solvents [J]. Chem. J. Chinese Universities, 2006, 27(11): 2144.
[15]	YU Jian-Guo, CAO Xue-Jing, ZHANG Heng-Bin, ZHANG Yu-Min, LI Ke-Chang. Electrooxidation of Hydroxypivalaldehyde at Ti/Sb₂O₅-SnO₂ Electrode [J]. Chem. J. Chinese Universities, 2006, 27(10): 1945.

Electrooxidation Study of 3-Picoline at PbO₂-Solid Polymer Electrolyte Composite Electrode

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments