Synthesis and Photochromism Property of Three Naphthacenequinone Phenolic Resins

Abstract

Abstract: Three naphthacenequinone photochromic phenolic resins, naphthacenequinone phenolic resin(2), methyl-naphthacenequinone phenolic resin(3) and chloro-naphthacenequinone phenolic resin(4) were synthesized by an one-step method, i.e. the reaction between 6-chloro-5,12-naphthacenequinone(1) and phenolic resins. The polymers have similar photochromic properties in THF solution with photochromic compound 6-phenoxy-5,12-naphthacenequinone. It was found that the substituents attaching to the main chain backbone of the polymer have a slight effect on the reaction and rate of photoisomerization of polymers. The rate constants were influenced by the molecular weight.

Key words: Naphthacenequinone, Phenolic resin, Photochromism, Photoisomerization

CLC Number:

O632

TrendMD:

LIAN Hui-Qin, WU Xue. Synthesis and Photochromism Property of Three Naphthacenequinone Phenolic Resins[J]. Chem. J. Chinese Universities, 2004, 25(9): 1740.

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Synthesis and Photochromism Property of Three Naphthacenequinone Phenolic Resins

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