Synthesis and Thermal Properties of PEEK-PEDEK Block Copolymers

Abstract

Abstract: A series of PEEK-PEDEK block copolymers were synthesized by one step method. Their crystallization and melting behavior were analyzed by Differential Scanning Calorimeter (DSC) and Wide Angle X-ray Diffraction (WAXD). The results show that the glass transition temperature of the copolymer increases obviously as a result of the introduction of biphenyl (BP) units. With the increasing of BP molar fraction,the melting point presents a down and up trend whereas the lowest melting point turns out at a point where the molar fraction of biphenyl is 20%.

Key words: PEEK, Block copolymer, DSC, WAXD

CLC Number:

O631

TrendMD:

WANG Han-Fu, ZHAO Xiao-Gang, LIU Xin-Cai, CHEN Liang, WANG Li-Feng, CHEN Chun-Hai, WU Zhong-Wen. Synthesis and Thermal Properties of PEEK-PEDEK Block Copolymers[J]. Chem. J. Chinese Universities, 2004, 25(6): 1156.

[1]	FAN Juanjuan, HAN Yuanyuan, CUI Jie. Monte Carlo Simulation of the Transformation Control of ABC Triblock Copolymer Micelles from Multicompartment Structure to Multicore Structure [J]. Chem. J. Chinese Universities, 2021, 42(3): 857.
[2]	SHI Xiaoyu, WANG Songmeng, LIU Lingyan, CHANG Weixing, LI Jing. Controllable Synthesis of Amphiphilic Block Copolymer PMnEOS-b-PAA and co-Assembly Morphologies of PMDEOS-b-PAA/PS-b-PAA [J]. Chem. J. Chinese Universities, 2020, 41(11): 2545.
[3]	CHENG Qinwen, YUAN Bo, ZHU Xiangdong, ZHANG Kai, ZHANG Xingdong. Surface Elemental Compositions and in Vitro Bioactivities of the PEEK Materials with Various Sulfonation and Alkali Treatments [J]. Chem. J. Chinese Universities, 2019, 40(8): 1757.
[4]	WANG Lin, ZHANG Yanhui, Arzugul Muslim, LAN Haidie. Morphology and Size Regulation of Polyaniline Induced by PS-b-P2VP as Template and Its Electrochemical Characters [J]. Chem. J. Chinese Universities, 2019, 40(8): 1748.
[5]	FENG Wenya, QIAO Juan, QI Li, LI Zhiwei. Sepatation of Antipyretic Analgesics by CapillaryElectrochromatography with Block Copolymer Coating^† [J]. Chem. J. Chinese Universities, 2018, 39(8): 1640.
[6]	ZHAO Junqiang, YAN Caixia, CHEN Ze, YANG Ning, FENG Xia, ZHAO Yiping, CHEN Li. Synthesis and Self-assembly Properties of Intracellular Redox Bioresponsive Block Copolymers with Hepatoma-targeting Groups^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1592.
[7]	RONG Jingjing,MA Lan,ZHU Youliang,HUANG Yineng,SUN Zhaoyan. Simulation of Perforated Lamelar Structures of Diblock Copolymer Induced by Surface Patterns^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2805.
[8]	ZHANG Yixin, WANG Mengxue, ZHANG Zheyuan, MI Puke, WANG Tinglan. Polyethylene-b-poly(ethylene/1-octene) Block Copolymer Prepared via Novel Dinuclear FI/Nickel(Ⅱ) α-Diiminecatalytic Systems [J]. Chem. J. Chinese Universities, 2017, 38(8): 1497.
[9]	LU Zhiwei, CHEN Shun, JU Yanyun, ZHANG Yang, XIONG Chuanxi, DONG Lijie. Synthesis and Properties of PS-b-P(DMS-stat-VMS) Block Copolymer [J]. Chem. J. Chinese Universities, 2017, 38(8): 1484.
[10]	DONG Xiaoming, YUAN Baoming, CHEN Bingpeng, HE Chaoliang, WANG Jincheng, CHEN Xuesi. In vitro Antibacterial Activity of PLGA-PEG-PLGA Thermosensitive Hydrogels Loaded with Vancomycin [J]. Chem. J. Chinese Universities, 2017, 38(5): 866.
[11]	WANG Xiaoqing, LING Jun, SHEN Zhiquan. Synthesis and Self-assembly of Thermoplastic Elastomer Poly(ε-decalactone)-Poly(L-lactide)-PEG with Rare Earth Catalyst^† [J]. Chem. J. Chinese Universities, 2016, 37(6): 1182.
[12]	WANG Yingying, CUI Jie, HAN Yuanyuan, JIANG Wei, SUN Yingchun. Monte Carlo Simulation on Self-assembly of AB Diblock Copolymers/Nanoparticles Complex Confined in Parallel Walls^† [J]. Chem. J. Chinese Universities, 2016, 37(5): 1010.
[13]	ZHANG Lixin, WANG Jintao, YANG Yongfang, ZHAO Hanying. Novel Method of Preparation of Diblock Copolymers with Disulfide Bonds at Junction Points^† [J]. Chem. J. Chinese Universities, 2016, 37(1): 161.
[14]	LIU Dongmei, DAI Lijun, DUAN Xiaozheng, SHI Tongfei, ZHANG Hanzhuang. Monte Carlo Simulation of Interfacial Properties in Homopolymer/Diblock Copolymer/Homopolymer Ternary Polymer Blends^† [J]. Chem. J. Chinese Universities, 2015, 36(9): 1752.
[15]	ZHANG Lili, CHEN Qiaoyue, ZHOU Hengwei, SHI Tongfei, HUANG Yineng. Influences of Topological Chain Structures to the Crystallization of Block Copolymers^† [J]. Chem. J. Chinese Universities, 2015, 36(9): 1832.

Synthesis and Thermal Properties of PEEK-PEDEK Block Copolymers

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments