Chem. J. Chinese Universities ›› 2004, Vol. 25 ›› Issue (6): 1142.

• Articles • Previous Articles     Next Articles

Effectof UV Illumination Treatment on Surface Photovoltaic Properties of TiO2 Films

FENG Wen- Hui1, SONG Yan- Lin1, WANG De- Jun2, ZHAI Jin1, JIANG Lei1   

  1. 1 .Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080,China; 2 .Collegeof Chemistry, Jilin University, Changchun1 100023,China
  • Received:2003-06-10 Online:2004-06-24 Published:2004-06-24

Abstract: Ti O2 films and N- doped Ti O2 films were prepared by magnetron sputtering methodology.The films were illuminated at365 nm for5— 20 min followed by the measurementof contactangles and surface photovoltage spectroscopy.The results show thatfor n- type Ti O2 film,UV illumination treatment can in- crease the photovoltage,while for p- type Ti O2 film,such treatment can decreases the photovoltage.The photovoltaic changing was explained by Ti— OH group increasing due to photo- induced hydrophility.For n- type Ti O2 film,Ti— OH groups can increase the photo- induced charge separation and thus iucrease the photovoltage;for p- type Ti O2 film,Ti—OH groups decrease the photo- induced charge separation and thus decrease the photovoltage.

Key words: TiO2 film, N-doped TiO2 film, Hydrophilicity, Photovoltage

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