Synthesis and Structure of a New Open Metal-organic-inorganic Hybrid Framework [Sn(SO4)(BDC)(H2O)](BDC=Terephthalic acid)

Chem. J. Chinese Universities ›› 2003, Vol. 24 ›› Issue (9): 1555.

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Synthesis and Structure of a New Open Metal-organic-inorganic Hybrid Framework [Sn(SO₄)(BDC)(H₂O)](BDC=Terephthalic acid)

SUN Jin-Yu^1,2, ZHOU Ya-Ming¹, CHEN Zhen-Xia¹, TU Bo¹, WENG Lin-Hong¹, ZHAO Dong-Yuan¹

1. Molecular Catalysis & Innovate Materials Lab, Department of Chemistry, Fudan University, Shanghai 200433, China;
2. Department of Chemistry, Liaoning University, Shenyang 11003
6. China

Received:2003-01-15 Online:2003-09-24 Published:2003-09-24

Abstract

Abstract: Anew coordination polymer [Sn(SO₄)(BDC)(H₂O)](BDC=terephthalic acid) with two dimensional (2D) open metal-organic-inganic hybrid framework structure has solvothermally prepared in N, N-dimethylformamide solution at 160℃. The structure determined from X-ray single crystal diffraction has space group P2₁of monoclinic system with a=0. 6816(5),b=1. 7628(14), c=0. 7722(6) nm, β=103. 7°, V=0. 9012(12) nm³, Z=4, D_c= l. 569 Mg/m³; R₁= 0. 0514[I>2σ(I)], R_w=0.1381. The product is characteristic of 2D channels with 2D wavy layer structure.

Key words: Metal-organic framework, Sn complex, Coordination polymer, Synthesis, Structure

CLC Number:

O641

TrendMD:

SUN Jin-Yu, ZHOU Ya-Ming, CHEN Zhen-Xia, TU Bo, WENG Lin-Hong, ZHAO Dong-Yuan. Synthesis and Structure of a New Open Metal-organic-inorganic Hybrid Framework [Sn(SO₄)(BDC)(H₂O)](BDC=Terephthalic acid)[J]. Chem. J. Chinese Universities, 2003, 24(9): 1555.

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Synthesis and Structure of a New Open Metal-organic-inorganic Hybrid Framework [Sn(SO₄)(BDC)(H₂O)](BDC=Terephthalic acid)

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