Studies on the Synthesis and Properties of Dihydroxy-di(hydroxyethoxy)calix Arene

Chem. J. Chinese Universities ›› 2003, Vol. 24 ›› Issue (2): 278.

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Studies on the Synthesis and Properties of Dihydroxy-di(hydroxyethoxy)calix Arene

LU Kui¹, ZHAN Hai-Jun¹, ZHOU Zhi-Xian², WU Yang-Jie²

1. Department of Chemistry and Chemical Engineering, Zhengzhou Institute of Technology, Zhengzhou 450052, China;
2. Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China

Received:2001-12-03 Online:2003-02-24 Published:2003-02-24

Abstract

Abstract: A new compound, 25,27-dihydroxy-26,28-di(hydroxyethoxy) calix arene, was obtained by the reaction of calixarene with iodoethanol. Its structure was characterized by IR, UV, MS, ¹HNMR and ¹³C NMR spectra. The coordination behavior of the product with 4 kinds of rare earth metal(Ⅲ) nitrates in acetonitrile was studied by using fluorescence spectrometry. The stability constants(lgK_S) of the complexes of the product with rare earth metal(Ⅲ) nitrates and the Gibbs free energy change(-ΔG°) of the coordination reactions were calculated according to the modified Hilderbrand-Benesi equation. The results indicated that the coordination ability of the product with rare earth metal(Ⅲ) nitrates were stronger.

Key words: Dihydroxy-26,28-di(hydroxyethoxy)calix arene, Synthesis, Coordination

CLC Number:

O641.4

TrendMD:

LU Kui, ZHAN Hai-Jun, ZHOU Zhi-Xian, WU Yang-Jie. Studies on the Synthesis and Properties of Dihydroxy-di(hydroxyethoxy)calix Arene[J]. Chem. J. Chinese Universities, 2003, 24(2): 278.

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Studies on the Synthesis and Properties of Dihydroxy-di(hydroxyethoxy)calix Arene

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