Chem. J. Chinese Universities ›› 2003, Vol. 24 ›› Issue (12): 2275.

• Articles • Previous Articles     Next Articles

Resonant Two-photon Ionization Spectra of van der Waals Complexes C6H4(CH32:Ar, N2, NH3(ND3)

HU Yi-Hua1, CHEN Li1, WU Huai-Xuan1, WANG Xiao-Juan1, LIU Mei-Xi1, YANG Shi-He2   

  1. 1. Department of Applied Physics, Guangdong University of Technology, Guangzhou 510090, China;
    2. Department of Chemistry, Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China
  • Received:2002-12-16 Online:2003-12-24 Published:2003-12-24

Abstract: Resonant two-photon ionization spectra of van der Waals complexes C6H4(CH3)2:Ar, N2, NH3were reported by using one-color resonant ionization technique, together with time-of-flight mass spectrometry, in supersonic molecular beam. All observed bands were rationally assigned by calculated levels, isotope effect, and spectral analysis. According to the spectra assignment, the frequencies of van der waals vibrations for these complexes were obtained.

Key words: Resonant photo-ionization spectra, van der Waals complex, Time-of-flight mass spectrometry

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