Synthesis of Solid Supramolecular Complex of Cyclohexyl Amino Modified β-Cyclodextrin with Oxazine and Its Luminescent Property

Chem. J. Chinese Universities ›› 2002, Vol. 23 ›› Issue (3): 407.

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Synthesis of Solid Supramolecular Complex of Cyclohexyl Amino Modified β-Cyclodextrin with Oxazine and Its Luminescent Property

KANG Shi-Zhao¹, ZHAO Yan-LIU Yu¹, WANG Ji-You¹

1. Department of Chemistry, Nankai University, Tianjin 300071, China;
2. Department of Physics, Nankai University, Tianjin 300071, China

Received:2000-12-15 Online:2002-03-24 Published:2002-03-24

Abstract

Abstract: The solid supramolcular complex of a novel β-cyclodextrin derivative(2) with oxazine was synthesized and characterized by means of elemental analysis, FTIR, ¹H NMR and TG. The results obtained show that supramolecular complex formed by compound 2 with oxazine is 1:1 stoichiometry. We also studied the luminescent property of the supramolecular complex. As compared with oxazine, the emission wavelength of supramolecular complex produces a blue shift of 155 nm. Meanwhile, its luminescence intensity is 4.9 times more than that of oxazine and the width of the fluorescence peak is narrowed to 51 nm.

Key words: Cyxlodextrin derivative, Supramolecular complex, Laser dye

CLC Number:

O641.4

TrendMD:

KANG Shi-Zhao, ZHAO Yan-LIU Yu, WANG Ji-You . Synthesis of Solid Supramolecular Complex of Cyclohexyl Amino Modified β-Cyclodextrin with Oxazine and Its Luminescent Property[J]. Chem. J. Chinese Universities, 2002, 23(3): 407.

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Synthesis of Solid Supramolecular Complex of Cyclohexyl Amino Modified β-Cyclodextrin with Oxazine and Its Luminescent Property

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