Racemic Isopropanolamine Templated Synthesis of a 2-Dimensional Layered Compound Al3P4O16· [NH3CH2CH(OH)CH3]2 · [NH4] from Various Non aqueous Solvents

Abstract

Abstract: A 2D layered aluminophosphate Al₃P₄O₁₆· [NH₃CH₂ CH(OH)CH₃]₂· [NH₄] containing [NH₃CH₂CH(OH)CH₃]⁺ and [NH₄]⁺ cations has been synthesized using racemic isopropanolamine as the template from several different non aqueous solvents. The compound has been characterized by single crystal structure analysis. Its space group is P2₁/m with a=0.89981(6)nm, b=1.47880(10)nm, c=0.97372(7)nm, β=104.790(2)° and V=1.25274(15)nm³. The structure consists of [Al₃P₄O₁₆]^3- macroanionic sheets stacked in an AAAAsequence and two types of cations, racemic [NH₃CH₂CH(OH)CH₃]⁺ and [NH₄]⁺, are located between the inorganic layers. The individual macroanionic sheet contains AlO₄ and PO₄ tetrahedral units in the ratio of 3/4 and all the AlO₄ vertices are shared, but each PO₄ has one terminal POgroup. Additional characterization of the compound by XRD, FTIR, ICPand TGAis also described.

Key words: Non-aqueous solvents, Layered aluminophosphate, Template, Synthesis, Structure, Racemie, Isopropanolamine

CLC Number:

O612

TrendMD:

CHEN Wei, YUAN Hong-Ming, SHI Zhan, ZOU Yong-Cun, CHEN Jie-Sheng, XU Ru-Ren . Racemic Isopropanolamine Templated Synthesis of a 2-Dimensional Layered Compound Al₃P₄O₁₆· [NH₃CH₂CH(OH)CH₃]₂ · [NH₄] from Various Non aqueous Solvents[J]. Chem. J. Chinese Universities, 2001, 22(6): 892.

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Racemic Isopropanolamine Templated Synthesis of a 2-Dimensional Layered Compound Al₃P₄O₁₆· [NH₃CH₂CH(OH)CH₃]₂ · [NH₄] from Various Non aqueous Solvents

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