Synthesis of 1,3-Bis(aryloxy acetyl)-1,3,2-diazaphospholidine-2-sulfide(selenide) Derivatives and Study of Their Herbicidal Activity

Abstract

Abstract: Aseries of new five membered phosphorus heterocycles were synthesized by cyclizing reaction of P(NEt-2)₃ with substrates containing diamino groups.The products were characterized by elemental analysis and spectrascopy. The preliminary bioassays showed that some compounds possessed a good selective herbicidal activity. In addition for the first time, the rearrangement of P⁼Se to P-Se in such phosphorus heterocycle was found, and the structure of the product together with intermolecular hydrogen bonds was confirmed by X-ray diffraction.

Key words: Cyclizing reaction, Five-membered phosphorus heterocycle, Herbicidal activity, Rearran-gement of P=Se to P-Se, X-Ray diffraction

CLC Number:

O626

TrendMD:

DENG Sheng-Lou, CHEN Ru-Yu, YANG Xiu-Feng . Synthesis of 1,3-Bis(aryloxy acetyl)-1,3,2-diazaphospholidine-2-sulfide(selenide) Derivatives and Study of Their Herbicidal Activity[J]. Chem. J. Chinese Universities, 2001, 22(11): 1833.

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Synthesis of 1,3-Bis(aryloxy acetyl)-1,3,2-diazaphospholidine-2-sulfide(selenide) Derivatives and Study of Their Herbicidal Activity

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