Studies on the Synthesis of 1-Aryloxy(α-substituted)acetyl-3-(substituted)- phenyl-2-diethylamino-2-sulfide(selenide)-1,3,2- diazaphospholidine-4-one and Their Herbicidal Activities

Abstract

Abstract: In order to look for a new herbicide, a series of novel phosphorus heterocyclic compounds have been prepared by the reaction of P(NEt₂)₃ with compounds containing 1,2 diamino groups at a high temperature. The structures of compounds Ⅱ were characterized by ¹H NMR and elemental analysis, some of which were characterized by ³¹P NMR and MS. The compound Ⅱl was analyzed by X-ray diffraction. The coplanar heterocycle and d_π-p_π electronic phenomenon of P_N bond were found. The preliminary biological tests indicated that some of them showed a better selective herbicidal activity.

Key words: Cyclocondensation, Five membered phosphorusheterocycle, X-ray diffraction, Herbicidal activity

CLC Number:

O626

TrendMD:

DENG Sheng-Lou, CHEN Ru-Yu, YANG Xiu-Feng . Studies on the Synthesis of 1-Aryloxy(α-substituted)acetyl-3-(substituted)- phenyl-2-diethylamino-2-sulfide(selenide)-1,3,2- diazaphospholidine-4-one and Their Herbicidal Activities[J]. Chem. J. Chinese Universities, 2000, 21(11): 1679.

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Studies on the Synthesis of 1-Aryloxy(α-substituted)acetyl-3-(substituted)- phenyl-2-diethylamino-2-sulfide(selenide)-1,3,2- diazaphospholidine-4-one and Their Herbicidal Activities

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