Preparation and Characterization of Poly(ethylene oxide)/Montmorillonite Intercalation Compound

Abstract

Abstract: In this paper, poly(ethylene oxide)/montmorillonite intercalation compound was prepared through solution and melting intercalating. The intercalation compound was characterized by XRD, IR and DSC, etc. PEO molecule couold react with Na⁺to form a coordination complex and it was in a spiral conformation between montmorillonite layers, so the PEO molecule could not be extracted by the solvent. As the molecular thermal action was restricted in the montmorillonite gallery, the melting peak of the PEO crystaL In intercalation compound was decreased.

Key words: Poly(ethylene oxide), Montmorillonite, Nonometer intercalation compound

CLC Number:

O631

TrendMD:

WANG Yi-Zhong, WU Bao-Hua, YU Ding-Sheng . Preparation and Characterization of Poly(ethylene oxide)/Montmorillonite Intercalation Compound[J]. Chem. J. Chinese Universities, 1999, 20(7): 1143.

[1]	XU Huan, KE Lyu, TANG Mengke, SHANG Han, XU Wenxuan, ZHANG Zilin, FU Yanan, HAN Guangdong, CUI Jinsheng, YANG Haoran, GAO Jiefeng, ZHANG Shenghui, HE Xinjian. In⁃situ Liquid Exfoliation of Montmorillonite Nanosheets in Poly（lactic acid） to Resist Oxygen Permeation [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220316.
[2]	ZHANG Jihua,WANG Chao,ZAO Weitao,LI Li,LIU Xiaoyan,YANG Yuan,WANG Hao. Preparation of High-performance Montmorillonite/hydrogenated Butadiene-acrylonitrile Rubber by Using Electrostatic Interfaces [J]. Chem. J. Chinese Universities, 2020, 41(4): 803.
[3]	LUAN Jingde, LIU Yawei, ZHANG Chengyu, KE Xin. Synchronization Capture of Zn²⁺ and p-Nitrophenyl Phenol on Montmorillonite Composites^† [J]. Chem. J. Chinese Universities, 2018, 39(2): 270.
[4]	LI Tingting, ZHAO Lele, WANG Ruili, ZHANG Shuqiu. Preparation and in vitro Release of Ketoprofen/acid-montmorillonite^† [J]. Chem. J. Chinese Universities, 2017, 38(5): 722.
[5]	LI Xingjian,JU Yunpeng,CHANG Degong,ZHANG Yiheng. Preparation and Properties of Flame Retardant Waterborne Polyurethane Nanocomposites via Click Reaction^† [J]. Chem. J. Chinese Universities, 2016, 37(8): 1580.
[6]	YU Tao, HAN Yu, WANG Hui, XIONG Shizhao, XIE Kai, GUO Qingpeng. Preparation and Lithium Ion Transport Behavior for Li_1.5Al_0.5Ge_1.5(PO₄)₃ Based Solid Composite Electrolyte [J]. Chem. J. Chinese Universities, 2016, 37(2): 306.
[7]	XIE Yu, LÜ Zhong-Yuan, SUN Zhao-Yan, AN Li-Jia. Dissipative Particle Dynamics Simulation Study on the Micellization and Gelation Behavior of PEO-PPO-PEO Solution [J]. Chem. J. Chinese Universities, 2013, 34(6): 1454.
[8]	XIE Yu, LV Zhong-Yuan, SUN Zhao-Yan, AN Li-Jia, LI Xiu-Hong, WU Zhong-Hua. Gel Structure of the 17R4/F127 Mixed Solutions [J]. Chem. J. Chinese Universities, 2013, 34(6): 1521.
[9]	XIONG Zu-Jiang, ZHANG Xiu-Qin, LIU Guo-Ming, ZHAO Ying, WANG Rui, WANG Du-Jin. Crystallization and Tensile Behavior of Poly(L-lactide)/ Poly(ethylene oxide) Blend [J]. Chem. J. Chinese Universities, 2013, 34(5): 1288.
[10]	RAN Shi-Ya, XU Yuan-Yuan, GUO Zheng-Hong, FANG Zheng-Ping. Synergistic Flame Retardant of Acid or Alkali-treated Montmrillonite/Phosphate Flame Retardant in PC/ABS Blends [J]. Chem. J. Chinese Universities, 2013, 34(2): 467.
[11]	SHAN Xue-Ying, TAI Qi-Long, HU Yuan, SONG Lei, LU Siu-Ming. Preparation and Property of Inherent Flame Retardant Polystyrene/Clay Nanocomposites [J]. Chem. J. Chinese Universities, 2013, 34(10): 2431.
[12]	DUAN Shu-E, ZHAI Yun-Hui, QU Ying-Juan, MA Ming-Yang. Synthesis and Antibacterial Activity of Silver-histidine Complex Doped Montmorillonite Antibacterial Agent [J]. Chem. J. Chinese Universities, 2012, 33(12): 2617.
[13]	JIN Lan-Ying, JIANG Yan-Xia*, LIAO Hong-Gang, ZENG Dong-Mei, SUN Shi-Gang. FTIR Spectroscopic Studies of PEO-based Polymer Electrolyte with Ionic Liquid [J]. Chem. J. Chinese Universities, 2009, 30(4): 767.
[14]	YE Ling*, ZHANG Jing-Yang. Chelate Regulatory ζ-potentials of Montmorilloniteand Its Adsorption Capacity for Cr(Ⅲ) [J]. Chem. J. Chinese Universities, 2009, 30(12): 2478.
[15]	MAO Jing, GAN Zhi-Hua*. Synthesis and Controlled Drug Release of Amphiphilic Graft Copolymers PEO-b-PGL-g-PCL [J]. Chem. J. Chinese Universities, 2009, 30(11): 2291.

Preparation and Characterization of Poly(ethylene oxide)/Montmorillonite Intercalation Compound

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments