Synthesis of an Amphiphilic BifunctionaL INitiatorwith an Aromatic Group

Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (6): 993.

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Synthesis of an Amphiphilic BifunctionaL INitiatorwith an Aromatic Group

ZHOU Guang-Chang¹, HUANG Peng-Cheng², ZHU He-Sun³

1. College of Chemical Engineering and Materials Science, Beijing, Institute of Technology, Beijing, 100081;
2. Research Center of Materials Science, Beijing, Institute of Technology, Beijing, 100081;
3. Department of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing, 100083

Received:1998-06-29 Online:1999-06-24 Published:1999-06-24

Abstract

Abstract: An amphiphilic bifunctionaLINitiator with an aromatic group, which is used in free radicaLINterfacial copolymerization, p-toluoyl(3-carboxypropionyl)sebacoyl diperoxide(MBSD), was synthesized by the successive condensation of sebacoyl chloride with p-methylperoxybenzoic acid and monoperoxysuccinic acid under the catalysis of pyridine and further characterized by IR, ¹HNMR, MS, elemental analysis and the analysis of peroxide oxygen content.

Key words: Amphiphilic bifunctional initiator, Free radical interfacial copolymerization, p-Toluoyl(3-carboxypropionyl)sebacoyl diperoxide

CLC Number:

O631

TrendMD:

ZHOU Guang-Chang, HUANG Peng-Cheng, ZHU He-Sun. Synthesis of an Amphiphilic BifunctionaL INitiatorwith an Aromatic Group[J]. Chem. J. Chinese Universities, 1999, 20(6): 993.

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Synthesis of an Amphiphilic BifunctionaL INitiatorwith an Aromatic Group

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