Enantioselective Permeation of Amino Acids Through β-Cyclodextrin Polymer Membranes

Abstract

Abstract: The β-cyclodextrin polymer membranes based on poly(vinyl alcohol) for enantioselective permeation of amino acids were described. The cyclodextrin membrane modified with acetic anhydride had higher permeation enantioselectivity of DL-amino acids than the unmodified membrane. The enhanced abilities were explained as a result of the additional steric hindrance effect besides inclusion. The maximum of enantiomeric excess for DLtryptophan was 25.4% with the permeation rate of D-tryptophan being up to 1.48×10^-5g·mm^-2h^-1.

Key words: β-Cyclodextrin, β-Cyclodextrin polymer membrane, Membrane separation, Enantiomeric resolution, Amino acids

CLC Number:

O647.2
TQ028.8

TrendMD:

LONG Yuan-De, HUANG Tian-Bao . Enantioselective Permeation of Amino Acids Through β-Cyclodextrin Polymer Membranes[J]. Chem. J. Chinese Universities, 1999, 20(6): 884.

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Enantioselective Permeation of Amino Acids Through β-Cyclodextrin Polymer Membranes

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