Studies on Supramolecular Chemistry of Calixarenes (Ⅰ) Liquid Membrane Transport of K+, Na+Ions with p-tert-Butylcalix[n]arenes and Their Derivatives as Carriers

Abstract

Abstract: The liquid membrane transports of K⁺ions by p-tert-butylcalix arene as carrier are investigated by the bubbling pseudo-emulsion liquid membrane. This transport process is a protoncoupled transport with a coupled flow of protons in opposite direction. The driving force for the transport is the pHgradient between the source phase and the receiving phase. The selected transport for K⁺ion or Na⁺ion by p-tert-butylcalix[n]arene(n=4, 6, 8) as carriers are investigated.

Key words: Calixarene, Liquid membrane, Protonscoupled transport

CLC Number:

O625.11

TrendMD:

SHI Xian-Fa, WANG Yu-Ping, LIU Yan-Sheng, JIANG Zhong-Liang, TAO Ling, SUN Hong-Bao . Studies on Supramolecular Chemistry of Calixarenes (Ⅰ) Liquid Membrane Transport of K⁺, Na⁺Ions with p-tert-Butylcalix[n]arenes and Their Derivatives as Carriers[J]. Chem. J. Chinese Universities, 1999, 20(2): 193.

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Studies on Supramolecular Chemistry of Calixarenes (Ⅰ) Liquid Membrane Transport of K⁺, Na⁺Ions with p-tert-Butylcalix[n]arenes and Their Derivatives as Carriers

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