Electrochemical Synthesis and Characterization of Soluble C60Derivative

Abstract

Abstract: A new C₆₀derivative was synthesized by means of electrochemistry, which exhibits greater water-solubility and remains stable in water and air. And very broad white light spectrum from this derivative has been observed. The bright white light emission of the new material results from a perturbation to the normal C₆₀molecule due to the Jahn-Teller distortion of symmetry structure and the interaction between C₆₀and -OH . And negative charges related to electrolysis product have been proved by using of electrophoresis. According to the infrared and Near-infrared spectrum the derivative contains hydroxyl groups. And XPS spectrum, 1³CNMR spectrum prove the derivative contains ester carbons.

Key words: C₆₀, Water soluble C₆₀derivative, Electrochemical synthesis, Photoluminescence

CLC Number:

O644.19

TrendMD:

ZHENG Ning, YU Zhan-Jun, LI Lin-Song, ZHOU Shi-Hong, HAN Li, LI Tie-Jin . Electrochemical Synthesis and Characterization of Soluble C₆₀Derivative[J]. Chem. J. Chinese Universities, 1999, 20(11): 1759.

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Electrochemical Synthesis and Characterization of Soluble C₆₀Derivative

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