Preparation, Structure Characterization and Bioassay of Tris(2-methyl-2-phenylpropyl)tin Carboxylates

Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (11): 1743.

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Preparation, Structure Characterization and Bioassay of Tris(2-methyl-2-phenylpropyl)tin Carboxylates

ZHANG Shu-Kui¹, CHEN Xue-Ren¹, LI Zhi-Chun¹, XIE Qing-Lan¹, ZHANG Zhao-Gui², DENG Feng-Jie²

1. State Key Laboratory of Elemento Organic Chemistry, Nankai University, Tianjin 300071, China;
2. Department of Chemistry, Nanchang University, Nanchang 330047, China

Received:1998-12-25 Online:1999-11-24 Published:1999-11-24

Abstract

Abstract: Fifteen tris(2-dimethyl-2-phenylpropyl)tin carboxylates were synthesized and characterized by IR and ¹HNMR. The results showed that these compounds may be four-coordinated and there are a linear relationship between ΔνCO2 and the Hammett constants (σ) of the para-substituents of the corresponding substituted benzoates. The bioasay tests show that neophyltin derivatives have a good acaricidal activity and may provide an acaricide for the better activity and economy.

Key words: Neophyltin, Carboxylate, Structure characterization, Bioassay, Acaricidal activity

CLC Number:

O627.42

TrendMD:

ZHANG Shu-Kui, CHEN Xue-Ren, LI Zhi-Chun, XIE Qing-Lan, ZHANG Zhao-Gui, DENG Feng-Jie . Preparation, Structure Characterization and Bioassay of Tris(2-methyl-2-phenylpropyl)tin Carboxylates[J]. Chem. J. Chinese Universities, 1999, 20(11): 1743.

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Preparation, Structure Characterization and Bioassay of Tris(2-methyl-2-phenylpropyl)tin Carboxylates

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