Studies on the Property of Oxygen-deficient Ferrite MFe2O4-δ

Abstract

Abstract: In the present paper, the lattice constant, magnetism, stability and reducing property of oxygen-deficient ferrite MFe₂O_4-δ (δ >0, M=Fe, Co, Mn, Ni) have been studied by XRDand Mssbauer methods. It is found that the lattice constant of MFe₂O_4-δ (δ>0) is larger than that of MFe₂O _4+δ, while its internal magnetic field is smaller than that of MFe₂O _4+δ. With increasing the deficiency degree δ, the lattice constant increased, and the internal magnetic field decreased. MFe₂O_4-δ is unstable in air at room temperature, but it can exist steadily in inert gas at low temperature(<673 K), MFe₂O_4-δ possesses very strong reducing power and can reduce CO₂ to Cat 573 K.

Key words: Oxygen deficient ferrite, Lattice constant, Magnetism, Stability, Reducing property

CLC Number:

O611

TrendMD:

ZHANG Chun-Lei, LI Shuang, PENG Yan-Bing, WU Tong-Hao, ZHANG Mi-Lin, PENG Shao-Yi . Studies on the Property of Oxygen-deficient Ferrite MFe₂O_4-δ[J]. Chem. J. Chinese Universities, 1998, 19(10): 1537.

[1]	CHU Yuyi, LAN Chang, LUO Ergui, LIU Changpeng, GE Junjie, XING Wei. Single-atom Cerium Sites Designed for Durable Oxygen Reduction Reaction Catalyst with Weak Fenton Effect [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220294.
[2]	ZHENG Anni, JIN Lei, YANG Jiaqiang, WANG Zhaoyun, LI Weiqing, YANG Fangzu, ZHAN Dongping, TIAN Zhongqun. Effects of 5，5-Dimethylhydantoin on Electroless Copper Plating [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220191.
[3]	WANG Hongning, HUANG Li, QING Jiang, MA Tengzhou, JIANG Wei, HUANG Weiqiu, CHEN Ruoyu. Activation of Biochar from Cattail and the VOCs Adsorption Application [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210824.
[4]	LI Weihui, LI Haobo, ZENG Cheng, LIANG Haoyue, CHEN Jiajun, LI Junyong, LI Huiqiao. Hot-pressed PVDF-based Difunctional Protective Layer for Lithium Metal Anodes [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210629.
[5]	CHANG Sihui, CHEN Tao, ZHAO Liming, QIU Yongjun. Thermal Degradation Mechanism of Bio-based Polybutylactam Plasticized by Ionic Liquids [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220353.
[6]	GUO Biao, ZHAO Chencan, LIU Xinxin, YU Zhou, ZHOU Lijing, YUAN Hongming, ZHAO Zhen. Effects of Surface Hydrothermal Carbon Layer on the Photocatalytic Activity of Magnetic NiFe₂O₄ Octahedron [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220472.
[7]	XU Fei, LI Gangmei, HAN Songde, WANG Guoming. Photochromism and Photomagnetism in Two Dinuclear Lanthanide Complexes [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210337.
[8]	YUE Shengli, WU Guangbao, LI Xing, LI Kang, HUANG Gaosheng, TANG Yi, ZHOU Huiqiong. Research Progress of Quasi-two-dimensional Perovskite Solar Cells [J]. Chem. J. Chinese Universities, 2021, 42(6): 1648.
[9]	WANG Hongning, HUANG Li, SONG Fujiao, ZHU Ting, HUANG Weiqiu, ZHONG Jing, CHEN Ruoyu. Synthesis and VOCs Adsorption Properties of Hollow Carbon Nanospheres [J]. Chem. J. Chinese Universities, 2021, 42(6): 1704.
[10]	WANG Kunhua, YAO Jisong, YANG Junnan, SONG Yonghui, LIU Yuying, YAO Hongbin. Synthesis and Device Optimization of Highly Efficient Metal Halide Perovskite Light-emitting Diodes [J]. Chem. J. Chinese Universities, 2021, 42(5): 1464.
[11]	RUAN Zeyu, DU Shannan, HUANG Guozhang, TONG Mingliang, LIU Junliang. Atropisomerism and Magnetic Properties of an in situ Synthesized Chiral Nickel Complex [J]. Chem. J. Chinese Universities, 2021, 42(3): 709.
[12]	LIU Yao, DENG Zhengtao. Fast Synthesis of Highly Luminescent Two-dimensional Tin-halide Perovskites by Anti-solvent Method [J]. Chem. J. Chinese Universities, 2021, 42(12): 3774.
[13]	ZHANG Jun, WANG Bin, PAN Li, MA Zhe, LI Yuesheng. Synthesis and Properties of Imidazolium-based Polyethylene Ionomer [J]. Chem. J. Chinese Universities, 2020, 41(9): 2070.
[14]	WANG Tingting, LEI Yuhan, LIN Yujuan, HUANG Jialing, LIU Cuie, ZHENG Fengying, LI Shunxing. Preparation of Liposome-terminated CsPbX₃(X=Cl,Br,I) Nanocrystals and Applications in Light-emitting Diode Devices [J]. Chem. J. Chinese Universities, 2020, 41(8): 1896.
[15]	WU Chunxiao, AI Xin, CHEN Yingxin, CUI Zhiyuan, LI Feng. Effects of Introducing Halogen Atoms to Biphenylmethyl Radical on Photostability, Photophysical and Electroluminescent Properties ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 972.

Studies on the Property of Oxygen-deficient Ferrite MFe₂O_4-δ

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments