Studies on the Formation and Reactivity of(Na[Fe(CO)2C5H5]2)n

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (1): 21.

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Studies on the Formation and Reactivity of(Na[Fe(CO)₂C₅H₅]₂)_n

YAN Peng-Fei¹, GAO Jin-Sheng¹, LE Zheng-Yu¹, MAO Gui-jie²

1. Department of Chemistry, Heilongjiang University, Harbin, 150080;
2. The Center of Analysis and Testing, Heilongjiang University, Harbin, 150080

Received:1996-09-03 Online:1998-01-24 Published:1998-01-24

Abstract

Abstract: According to the reaction of [Fe(CO)₂C₅H₅]₂ with sodium amalgam (Na/Hg), the molecular structures of crystals and the IR data of L₃SnFe (CO)₂C₅H₅ (L=C₆H₁₁, C₆H₅),[ (C₅Me₅)₂Ln (CO)₂FeC₅H₅]₂(Ln=Dy, Gd, Sm, Nd, Pr) complexes, the process of forma tion of (Na[Fe (CO)₂C₅H₅]₂)_n, its structure changes and reaction regularities in the synthe ses of heteronuclear metal complexes were analyzed and discussed.

Key words: Polybis(cyclopentadienyldicarbonyliron)sodium, Reaction regularity, Heteronu clear metal complex

CLC Number:

O627.8

TrendMD:

YAN Peng-Fei, GAO Jin-Sheng, LE Zheng-Yu, MAO Gui-jie . Studies on the Formation and Reactivity of(Na[Fe(CO)₂C₅H₅]₂)_n[J]. Chem. J. Chinese Universities, 1998, 19(1): 21.

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Studies on the Formation and Reactivity of(Na[Fe(CO)₂C₅H₅]₂)_n

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