Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra-(para-hydroxyphenyl) Porphyrin Complexes

Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (8): 1375.

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Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra-(para-hydroxyphenyl) Porphyrin Complexes

SHI Tong-Shun, AN Qing-Da, XU Chun-Fang, LIU Guo-Fa, TENG Yong-Fu, QI Xiang-Li, YU Lian-Xiang

Department of Chemistry, Jilin University, Changchun 130023

Received:1996-07-28 Online:1997-08-24 Published:1997-08-24

Abstract

Abstract: The Fourier Transform infrared photoacoustic spectra of tetra-(para-hydro-xyphenyl) porphyrin and its Cr(III), Mn(III), Fe(III), Co(II), Ni (II), Cu (II) and Zn(II) complexes in the range 3700-200cm^-1 were measured and investigated. There exist intermolecular hydrogen bonds in the porphyrin and its complexes. The vibration coupling between the M-Nstretching and the porphyrin ring deformation appears at 250cm^-1. The band at 316cm^-1 is stretching vibration of M(III)-Cl. Metal sensitive bands were found at about 1550, 1350, 1076, 1000 and 250cm^-1.

Key words: Infrared photoacoustic spectrum, Transitional metal, Porphyrin complex

CLC Number:

O657.33

TrendMD:

SHI Tong-Shun, AN Qing-Da, XU Chun-Fang, LIU Guo-Fa, TENG Yong-Fu, QI Xiang-Li, YU Lian-Xiang . Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra-(para-hydroxyphenyl) Porphyrin Complexes[J]. Chem. J. Chinese Universities, 1997, 18(8): 1375.

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Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra-(para-hydroxyphenyl) Porphyrin Complexes

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