Evolution and Significance of Molecular Design Conception in the Development of Stereo-selective Transition-metal Complex Catalysts

Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (7): 1185.

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Evolution and Significance of Molecular Design Conception in the Development of Stereo-selective Transition-metal Complex Catalysts

WAN Hui-Lin, YUAN You-Zhu, GAO Jing-Xing, ZHANG Hong-Bin, ZHU Gui-Yun

Department of Chemistry, Institute of Physical Chemistry, State Key Laboratoryfor Physical Chemistry of the Solid Surface, Xiamen University, Xiamen 361005

Received:1997-02-14 Online:1997-07-24 Published:1997-07-24

Abstract

Abstract: The mutual promotion of the development of stereo-selective coordination cata-lysts involving transition-metal coordination compounds and the development of the concep-tion of molecular design of such catalysts was discussed, as illustrated by three typical typesof stereo-selective coordination catalysis, namely, asymmetric synthesis, stereo-selective co-ordination polymerization of α-olefins, and hydroformylation of α-olefins.With this discus-sion, it is shown that for the molecular design of certain types of stereo-selective coordina-tion catalysts, there has already been sound scientific basis for the development of computer-aided design (CAD).

Key words: Asymmetric synthesis, Stereo-selective coordination polymerization, Hydro-formylation, Catalyst molecule design

CLC Number:

O643.31

TrendMD:

WAN Hui-Lin, YUAN You-Zhu, GAO Jing-Xing, ZHANG Hong-Bin, ZHU Gui-Yun . Evolution and Significance of Molecular Design Conception in the Development of Stereo-selective Transition-metal Complex Catalysts[J]. Chem. J. Chinese Universities, 1997, 18(7): 1185.

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Evolution and Significance of Molecular Design Conception in the Development of Stereo-selective Transition-metal Complex Catalysts

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