Synthesis and Structure of the Three Dimensional Hetero-metallic Cyano Complex with Mixed-bridge

Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (7): 1019.

• Articles • Previous Articles Next Articles

Synthesis and Structure of the Three Dimensional Hetero-metallic Cyano Complex with Mixed-bridge

ZHANG Si-Wei¹, DUAN Chun-Ying¹, FU De-Gang¹, TANG Wen-Xia¹, HU Chun-Hua², CHEN Jian², ZHENG Pei-Ju²

1. State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjng University, Nanjing 210093;
2. Research Center of Analysis and Measurement, Fudan University, Shanghai 200433

Received:1997-01-28 Online:1997-07-24 Published:1997-07-24

Abstract

Abstract: The molecular-based magnetic complex {[Cu (1, 3-Pn)]₂ [Fe (CN)₆] (OH).3H₂O }_n, where 1, 3-Pn is 1, 3-diaminopropane, has been prepared and characterized by X-raycrystallography.It crystallizes in the monoclinic system, space group P2₁/n, with a =0.7577(3) nm, b=1.0698(1) nm, c=1.3000(2) nm, β=90.05°, V=1.0538(5) nm³,and Z =4.The result of the crystallography indicates that this complex has a three-dimen-sional structure.

Key words: Three-dimensional structure, Hetero-bimetallic cyano complex, Mixed-bridge, Disorder

CLC Number:

O614.12

TrendMD:

ZHANG Si-Wei, DUAN Chun-Ying, FU De-Gang, TANG Wen-Xia, HU Chun-Hua, CHEN Jian, ZHENG Pei-Ju. Synthesis and Structure of the Three Dimensional Hetero-metallic Cyano Complex with Mixed-bridge[J]. Chem. J. Chinese Universities, 1997, 18(7): 1019.

[1]	XU Xiaomu, ZHANG Xingshuai, CHEN Zhining, WANG Jing, GUO Yuzhong, HUANG Ruian, WANG Jianhua. Preparation of a Disordered Mesoporous Silicon Nanocomposite and Its Slow Activation Behavior^† [J]. Chem. J. Chinese Universities, 2017, 38(5): 713.
[2]	SUN Yan, WANG Bing. Molecular Recognition Mechanism of Chiral (S)-Ibuprofen’s Hydrogen Bonds Self-assembly Imprinted Polymer [J]. Chem. J. Chinese Universities, 2012, 33(04): 838.
[3]	WANG Chong, WANG Dian-Long*, WANG Qiu-Ming, CHEN Huan-Jun. Preparation and Electrochemical Performance of Three-dimensional Structure Foam Co3O4 [J]. Chem. J. Chinese Universities, 2010, 31(10): 2058.
[4]	DU Miao,YU Qiu-Ming,WANG Wan-Jie,ZHENG Qiang. Viscoelastic Relaxation and Phase Morphology of Linear Styrene-butadiene-styrene Triblock Copolymer [J]. Chem. J. Chinese Universities, 2006, 27(4): 753.
[5]	YANG Chi-Ming . Organic Chemistry in Neurodegenerative Disorders ——Physical Organic Chemistry and Bioorganic Free Radical Chemistry of Prion Protein [J]. Chem. J. Chinese Universities, 2002, 23(2): 243.
[6]	LU Yang, WANG Shu-Chun, ZHENG Qi-Tai, LIU Wei, LI Fang-Hua. Local Structural Disorder in the Organic Molecular Crystals [J]. Chem. J. Chinese Universities, 1997, 18(12): 1978.
[7]	LI Hong-Bin, ZHANG Xi, ZHANG Rui-Feng, ZHAO Bing, XU Wei-Qing, SHEN Jia-Cong, GAO Zhong-Min. Studies on the Ordeer-Disorder Transition in Reversed Duckweed Polymeric LB Films [J]. Chem. J. Chinese Universities, 1996, 17(1): 160.
[8]	WANG Jun, WANG Lian-Bo, JIANG Qing, LI Hong, XIANG Si-Fen, LIN Bing-Xiong . Structural Studies on Partially Disordered Layer Lattice of Zirconium Pillared Montmorillonite [J]. Chem. J. Chinese Universities, 1993, 14(7): 902.

Synthesis and Structure of the Three Dimensional Hetero-metallic Cyano Complex with Mixed-bridge

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 8

Recommended Articles

Metrics

Comments