Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (3): 357.

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Synthesis and Characterization of Bis(amine) Iron(Ⅱ) Porphyrins

ZHONG Xin-Hua1, FENG Yao-Yu2, HUANG Jie-Sheng1, SHEN Pan-Wen1   

  1. 1. Department of Chemistry, Nankai University, Tianjin University, Tianjin, 300072;
    2. Institute of Chemical Engineering, Tianjin University, Tianjin, 300072
  • Received:1996-03-01 Online:1997-03-24 Published:1997-03-24

Abstract: Aseries of bis(amine) iron(Ⅱ) porphyrin Fe(Ⅱ)TPP(NH2R)2 complexes (NH2R=PhNH2, C6H11NH2, n-BuNH2, PhCH2NH2, NHMe2; TPP=dianion of meso-tetraphenylporphyrin) were prepared by the reduction of Fe (Ⅲ) porphyrins with the correspondingamine in an antiformin system in air as well as by the sodium borohydride reduction method,respectively.The complexes were charaterized by UV-Vis, IRand elementary analysis, andsome important properties of them were discussed.

Key words: Bis(amine)iron(Ⅱ) porphyrin, Amine, Synthesis

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