Synthesis and Characterization of Layered Phosphotoantimonic Acid-Intercalated Cobalt Porphyrin and Its Catalytic Behaviour to Hydroperoxide Decomposition

Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (2): 167.

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Synthesis and Characterization of Layered Phosphotoantimonic Acid-Intercalated Cobalt Porphyrin and Its Catalytic Behaviour to Hydroperoxide Decomposition

HU Xi-Ming¹, CHEN Bi-Yun¹, Pl Zong-Xin¹, MEI Zhi-Qian¹, GU Guo-Bang¹, HUANG Zhong-Tao²

1. Department of Applied Chemistry, South China University of Technology, Guangzhou, 510641;
2. Department of Chemical Engineering, South China University of Technology, Guangzhou, 510641

Received:1996-03-07 Online:1997-02-24 Published:1997-02-24

Abstract

Abstract: Astepwise synthesis method was used to intercalate cobalt tetraphenylporphyrin into the layered phosphotoantimonic acid host material.The characterization of the purified sample layered phosphotoantimonic acid-intercalated cobalt porphyrin was made by the method of IR, powder XRD, UV-Vis and EPR.Layered phosphotoantimonic acid-intercalated cobalt porphyrin exhibits a fairly catalytic behaviour to hydroperoxide decotnposition, which indicates the intercalation of the porphyrin could result in the prevention of the formaaion of u-dimers and the increased catalytic capabilities.

Key words: Cobalt porphyrin, Layered phosphatoantimonic acid, Intercalation, Hydroperoxide, Catalytic behaviour

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HU Xi-Ming, CHEN Bi-Yun, Pl Zong-Xin, MEI Zhi-Qian, GU Guo-Bang, HUANG Zhong-Tao. Synthesis and Characterization of Layered Phosphotoantimonic Acid-Intercalated Cobalt Porphyrin and Its Catalytic Behaviour to Hydroperoxide Decomposition[J]. Chem. J. Chinese Universities, 1997, 18(2): 167.

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Synthesis and Characterization of Layered Phosphotoantimonic Acid-Intercalated Cobalt Porphyrin and Its Catalytic Behaviour to Hydroperoxide Decomposition

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