Preparation of Layered Phosphatoantimonic Acid-Intercalated Manganese Porphyrin and Catalytic Oxidation of Simmulated Cytochrome

Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (9): 1353.

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Preparation of Layered Phosphatoantimonic Acid-Intercalated Manganese Porphyrin and Catalytic Oxidation of Simmulated Cytochrome

HU Xi-Ming¹, PI Zong-Xin¹, MEI Zhi-Qian¹, GU Guo-Bang¹, HUANG Zhong-Tao²

1. Department of Applied Chemistry, South China University of Technology, Guangzhou, 510641;
2. Department of Chemical Engineering, South China University of Technology, Guangzhou, 510641

Received:1996-04-09 Online:1996-09-24 Published:1996-09-24

Abstract

Abstract: Manganese tetraphenylporphyrin as a guest molecule was intercalated in situ into the layered host material phosphatoantimonic acid.The porphyrin immobilized in the layered structure exhibits a fairly catalytic capability for the epoxidation of cyclohexene and the oxidation of n-octane by hydrogen peroxide, due to the prevention of the formation of μ-dimers.

Key words: Mangnese porphyrin, Layered phosphatoantimonic acid, Intercalation, Catalytic behaviour

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HU Xi-Ming, PI Zong-Xin, MEI Zhi-Qian, GU Guo-Bang, HUANG Zhong-Tao. Preparation of Layered Phosphatoantimonic Acid-Intercalated Manganese Porphyrin and Catalytic Oxidation of Simmulated Cytochrome[J]. Chem. J. Chinese Universities, 1996, 17(9): 1353.

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Preparation of Layered Phosphatoantimonic Acid-Intercalated Manganese Porphyrin and Catalytic Oxidation of Simmulated Cytochrome

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