Synthesis of Lanthanide Porphrin Coordination Compounds by Solid State Reaction

Abstract

Abstract: Synthesis of lanthanide porphyrin coordination compounds was described.The coordination compounds contain acetylacetonate-5,10,15,20-tetraphenylporphyrin ybtterbium,acetylacetonate-5.(p-hydroxyphenyl)-10,15,20-tri(p-methoxyphenyl) porphyrin lutetium acetylacetonate-5,10,15,20(p-methoxyphenyl) porphyrin europium and acetylacetonate5,10,15,20-(p-naphthyl)-tetra-benzoporphyrin erbium,The coordination compounds were characterized by elementary analysis, UV-Vis,IRspectra and ¹H NMRspectra.

Key words: Acetylacetone, Tetraphenylsubstituted porphyrin, Tetranaphthyl tetrabenzoporphyrin, Rare earth complex

TrendMD:

LIU Guo-Fa, TENG Yong-Fu, SHI Tong-Shun. Synthesis of Lanthanide Porphrin Coordination Compounds by Solid State Reaction[J]. Chem. J. Chinese Universities, 1996, 17(7): 1022.

[1]	ZHOU Yonghui, LI Yao, WU Yuxuan, TIAN Jing, XU Longquan, FEI Xu. Synthesis of A Novel Photoluminescence Self-healing Hydrogel [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210606.
[2]	XIAN Guoxuan, YU Yu’e, CHEN Yuqian, WAN Xiaoyu, WANG Suna, LU Jing. Coligand Induced Luminescent Cd-MOFs： Luminescence Enhancement Toward Acetylacetone and Quenching Toward Cr₂O₇^2- [J]. Chem. J. Chinese Universities, 2020, 41(12): 2725.
[3]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[4]	CHEN Hong, ZHAO Xuan, GAO Hui, ZHU Haidi, JIANG Lihong, LING Qidan. Synthesis of Red Light-emitting Hydrotalcite-like Compound and Its Application in LED^† [J]. Chem. J. Chinese Universities, 2015, 36(1): 41.
[5]	FANG Zhao, TANG Rui-Ren*, HUANG Ke-Long, ZHANG Rui-Rong. Autoxidation of Monoterpenes with Oxygen Catalyzed by Co(acac)₂ Supported on Silica Functionalized Imidazole [J]. Chem. J. Chinese Universities, 2009, 30(9): 1748.
[6]	DENG Rui-Ping^1,2, YU Jiang-Bo¹, ZHANG Hong-Jie¹*, LI Zhe-Feng^1,2, ZHOU Liang^1,2, PENG Ze-Ping^1,2, GUO Zhi-Yong^1,2. Investigation of Triboluminescence of Sm(TTA)₃phen and the Relationship Between Triboluminescence Phenomena of Rare Earth Complexes and Properties of Ligands [J]. Chem. J. Chinese Universities, 2007, 28(6): 1005.
[7]	CAI Zheng-Hong¹*, TANG Jing¹, TANG Yu², TAN Min-Yu², YU Kai-Bei³. Synthesis and Structure of Binuclear Cage-like Rare Earth Complex [Eu₂(TCM)₂(DMSO)₆]·2DMSO [J]. Chem. J. Chinese Universities, 2007, 28(10): 1836.
[8]	GUO Qian-Ling¹, QU Yi-Xin¹, MA Shu-Lan², ZHU Wen-Xiang². Synthesis, Crystal Structure and Characterization of Carboxylic Derivatives of Sulfonylcalix[4]arene [J]. Chem. J. Chinese Universities, 2006, 27(11): 2034.
[9]	WU Ying-Liang, HU Bin, JIANG Zu-Cheng . Studies on the Chemical Modification and Its Mechanism of Acetylacetone in Low Temperature ETV-ICP-AES [J]. Chem. J. Chinese Universities, 2004, 25(1): 50.
[10]	CHENG Jian-Hua, CUI Dong-Mei, CHEN Wen-Qi, HU Ning-Hai, TANG Tao, HUANG Bao-Tong . Synthesis and Crystal Structure of Bis(tetrahydrofurfurylindenyl) Lanthanide Chlorides [J]. Chem. J. Chinese Universities, 2003, 24(6): 973.
[11]	XU Qing-Hong, LI Hong-Wu, LI Lian-Sheng, ZOU Yong-Cun, XU Ru-Ren . A Study on Assembly of a Rare Earth Complex [C₅H₅NC₁₆H₃₃] [Eu（TTA）₄] in the Channel of Si-MCM-41 [J]. Chem. J. Chinese Universities, 2003, 24(10): 1758.
[12]	CUI Dong-Mei, TANG Tao, CHENG Jian-Hua, HU Ning-Hai, CHEN Wen-Qi, HUANG Bao-Tong. Synthesis and Crystal Structure of Cyclopentylindene Rare Earth Complex (C₅H₉C₉H₆)₃SmCl^-Li⁺(THF)₄ [J]. Chem. J. Chinese Universities, 2002, 23(2): 188.
[13]	WANG Dong-Mei, LIN Quan, FU Lian-She, LI Huan-Rong, CHU Zhen-Xing, YANG Bai . The Preparation and Property Studies of Transparent Resins Containing Rare Earth Terbium(Ⅲ) Complex [J]. Chem. J. Chinese Universities, 2001, 22(4): 695.
[14]	FENG Yun-Long, LIU Shi-Xiong . Syntheses and Spectral Properties of Two Complexes of Isonitrosoacetylacetone- N -arylimine and Crystal Structure of PdCl(C₆H₅-IAI)(C₆H₅NH₂) [J]. Chem. J. Chinese Universities, 2000, 21(10): 1455.
[15]	FAN Ying-Fang, YANG Pin . Coordination Field Analysis of the Polarized Luminescence Spectra of Tb³⁺ in Trigonal Na₃[Tb(C₄H₄O₅)₃]·2NaClO₄·6H₂O [J]. Chem. J. Chinese Universities, 1999, 20(8): 1266.

Synthesis of Lanthanide Porphrin Coordination Compounds by Solid State Reaction

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments