Preparation of Organoarsino-Containining Ferrocenyl Derivatives from the Quaternary Ammonium Salt

Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (2): 261.

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Preparation of Organoarsino-Containining Ferrocenyl Derivatives from the Quaternary Ammonium Salt

DU Hong-Guang, SHI Shu-Jian

Department of Applied Chemistry, Beijing University of Chemical Technology, Beijing 100029

Received:1995-02-17 Online:1996-02-24 Published:1996-02-24

Abstract

Abstract: The methiodide of 2-(dimethylaminomethyl) diphenylarsinoferrocene was allowed to react with a number of nucleophiles:sodium methoxide,sodium phenolate,substituted phenolates,piperidine and N-methylaniline.Eight new 2-substituted diphenylarsinoferrocenes were obtained.The structure of the products were determined by elementary analysis,¹H NMR,IRand MSspectra.

Key words: Organoarsine, Ferrocene derivatives, Ammonium methiodide, Nucleophilic substitution

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DU Hong-Guang, SHI Shu-Jian. Preparation of Organoarsino-Containining Ferrocenyl Derivatives from the Quaternary Ammonium Salt[J]. Chem. J. Chinese Universities, 1996, 17(2): 261.

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Preparation of Organoarsino-Containining Ferrocenyl Derivatives from the Quaternary Ammonium Salt

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