Multi-Functionalization of Vanadylorgano-phosphonate Through Intercalation

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (S1): 21.

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Multi-Functionalization of Vanadylorgano-phosphonate Through Intercalation

Tomokazu Iyoda¹, Takashi Shimura^1,2, Kenichiro Nakamura², Kazuhito Hashimoto^1,3, Akira Fujishima^1,3

1. Kanagawa Academy of Scinece and Technology, Atsugi, Kanagawa, 243-02, Japan;
2. Dept. of Optoengineering Tokai University, Hiratsuka, Kanagawa, 259-12, Japan;
3. Dept. of Applied Chemistry, the University of Tokyo, Tokyo 113, Japan

Received:1995-07-29 Online:1995-12-31 Published:1995-12-31

Abstract

Abstract:

The intercalation of various kinds of alcohols into vanadyl-organophosphate powder is investigated mainly by elementary analysis and X-ray diffraction measurement. Not only a series of fatty alcohols but also benzylalcohol derivatives are almost quantitatively intercalated with reasonable relationships between the size of the intercalators and the increasing layer spacing. Another useful preparative method for the host thin film is developed by electrochemical treatment of a conventional V₂O₅ thin film.

Key words: Vanadylorganophosphonate, Intercalation, Layer spacing, Host material, Electrochemical preparation

TrendMD:

Tomokazu Iyoda, Takashi Shimura, Kenichiro Nakamura, Kazuhito Hashimoto, Akira Fujishima. Multi-Functionalization of Vanadylorgano-phosphonate Through Intercalation[J]. Chem. J. Chinese Universities, 1995, 16(S1): 21.

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Multi-Functionalization of Vanadylorgano-phosphonate Through Intercalation

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