Controlled Terminationof Isobutylene Cationic Polymerization──The Transformation of Reactive End

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (9): 1485.

• Articles • Previous Articles Next Articles

Controlled Terminationof Isobutylene Cationic Polymerization──The Transformation of Reactive End

CAO Xian-Yi, WANG Qiang, WU Guang-Ying

Research Institute of Polymer Materials, Beijing University of Chemical Technology, Beijng, 100029

Received:1995-04-12 Revised:1995-05-31 Online:1995-09-24 Published:1995-09-24

Abstract

Abstract: The paper reported a novel method to control termination of isobutylene cationic polymerization, which can be called the transformation of reactive end(TRE).The reactive center of isobutylene propagation was completely transformed to stable diphenyl alkyl cation at 80℃ by reaction with 1,1-diphenyl ethylene,The end of one polymer chain was capped with only one DPE molecule no matter how amount of DPE was excess or equal to that of initiator.The product contained special double bond at the chain end.Model initiator, which was model of such cation initiated polymerization of isobutyl vinyl ether successfully.

Key words: Isobutylene, Cationic polymerization, Transformation of reactive end

TrendMD:

CAO Xian-Yi, WANG Qiang, WU Guang-Ying . Controlled Terminationof Isobutylene Cationic Polymerization──The Transformation of Reactive End[J]. Chem. J. Chinese Universities, 1995, 16(9): 1485.

[1]	YANG Yingjie, ZHANG Xiaorong, SUN Yuxue, LIU Jun, XIE Haiming. Synthesis of a Dual-lithium-salt Comb Polymer Electrolyte and Its Electrochemical Performance [J]. Chem. J. Chinese Universities, 2021, 42(9): 2861.
[2]	YE Lishaya, HUANG Yajiang, KONG Miqiu, LOU Fangli, YANG Qi, LI Guangxian. Effect of Amphiphilic Silica Rods on the Morphology of Immiscible Polyisobutylene/Polydimethylsiloxane Blends Under Simple Shear Flow [J]. Chem. J. Chinese Universities, 2017, 38(8): 1470.
[3]	PENG Xiao-Juan, HUANG Ya-Jiang*, HE Yu-Song, LUO Yong, YANG Qi, LI Guang\\|Xian. Effect of Silica Nanoparticles on the Morphology of Immiscible PIB/PDMS Blends in Confined Shear Flow [J]. Chem. J. Chinese Universities, 2011, 32(12): 2896.
[4]	PANG Lai-Xing, ZENG Zhao-Hua, YANG Jian-Wen, CHEN Yong-Lie . Thermal Polymerization of Urethane Vinyl Ethers Initiated by Diaryldiodonium Salt [J]. Chem. J. Chinese Universities, 2004, 25(11): 2153.
[5]	LU Jiang, LIANG Hui, ZHANG Rong-Fu. Living Cationic Polymerization of β-Pinene with1-Phenylethyl Chloride/TiCl₄/Ti(OiPr)₄ [J]. Chem. J. Chinese Universities, 2000, 21(12): 1932.
[6]	GUO Wen-Li, LI Shu-Xin, MA Yu-Hong, XU Rui-Qing, WU Guan-Ying. Complexation Competition in Cationic Polymerization with TiCl₄ Coinitiator [J]. Chem. J. Chinese Universities, 1998, 19(4): 642.
[7]	CAO Xian-Yi, ZHOU Xin-Ru, CHU Guang-Cheng, WU Guan-Ying. Carbocationic Reaction Between 2, 4, 4-Trimethy 1-2-chloropentane and 1, 1-Diphenyl Ethylene(Ⅰ)──Main Features of the Reaction [J]. Chem. J. Chinese Universities, 1997, 18(2): 329.
[8]	GUO Wen-Li, XU Rui-Qing, WU Guan-Ying . Cationic Polymerization of IBVE Initiated by Cl₂ TiCl₄/Toluene (Ⅰ)—Initiating Centers and the Role of Their Complex Competition in the Polymerization [J]. Chem. J. Chinese Universities, 1993, 14(10): 1460.
[9]	CAO Xian-Yi, ZHANG Chuan-Bai, WU Guan-Ying . Carbocationic Polymerization of Isobutylene by the Initiator System of Diethyl Aluminium Chloride/Benzyl Chloride/Pyridine [J]. Chem. J. Chinese Universities, 1993, 14(10): 1476.
[10]	Deng Yun-xiang, Lin Hua-yu, Higashimura T.. Studies on Polymerization of a-Pinene Initiated by a New System AlCl₃/Activator/Donors (Ⅰ)--AlCl₃/SbCl₃/Ester Initiating System [J]. Chem. J. Chinese Universities, 1991, 12(10): 1414.

Controlled Terminationof Isobutylene Cationic Polymerization──The Transformation of Reactive End

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 10

Recommended Articles

Metrics

Comments