The Cycle Reaction of Thiophosphoryl Substituted Thioureas with Some Reagents Containing Bifunctional Groups

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (9): 1405.

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The Cycle Reaction of Thiophosphoryl Substituted Thioureas with Some Reagents Containing Bifunctional Groups

YANG Hua-Zheng, LIU Hua-Yin, WU Ye

The Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071

Received:1994-09-29 Revised:1995-03-21 Online:1995-09-24 Published:1995-09-24

Abstract

Abstract: O-ethyl-N-isopropyl thiophosphoryl substituted thioureas reacted with chloroacetyl chloride,dichloro acetyl chloride,trichloro acetyl chloride and chloroethanal, in the presence of base to give corresponding thiazolidine and thiazole derivatives,respectively.It was found that different products were due to different structures of reactive reagents, and the effect of reactive condition on the assign of products was studied. The result of bioactivities indicates that some of compounds have herbicidal activity.

Key words: Thiophosphoryl thioureas, Thiazolidine, Cycle reaction

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YANG Hua-Zheng, LIU Hua-Yin, WU Ye . The Cycle Reaction of Thiophosphoryl Substituted Thioureas with Some Reagents Containing Bifunctional Groups[J]. Chem. J. Chinese Universities, 1995, 16(9): 1405.

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The Cycle Reaction of Thiophosphoryl Substituted Thioureas with Some Reagents Containing Bifunctional Groups

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