Synthesis,Characterization and Activity of a New Type Layered Microporous Materials──Pillared Anion Clay with Ga-W9-Co3

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (12): 1844.

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Synthesis,Characterization and Activity of a New Type Layered Microporous Materials──Pillared Anion Clay with Ga-W₉-Co₃

ZHANG Ji-Yu, YU Xin-Wu, ZHANG Shu-Yun, HU Chang-Wen, LIANG Zhao-Jun, WANG En-Bo

Department of Chemistry, Northeast Normal University, Changchun, 130024

Received:1995-05-29 Revised:1995-07-09 Online:1995-12-24 Published:1995-12-24

Abstract

Abstract: Tungstogallic heteropolyanion trisubstituted with transition metal cobalt was intercalated into ZnAl-NO₃ type anion clay by means of hydrothermal ion-exchange for the first time.IR spectra show that Keggin structure of the intercalated hyteropolyanion was kept perfect. Powder X-ray diffraction confirms that the intercalation reaction takes place and the gallery height of intercalated product is 0.99±0.01 nm.Catalytical tests exhibit that the intercalated derivative shows a higher catalytic activity for the formation of DOP.

Key words: Transition metal, Trisubstituted heteropolyanion, Intercalation, Anion clay

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ZHANG Ji-Yu, YU Xin-Wu, ZHANG Shu-Yun, HU Chang-Wen, LIANG Zhao-Jun, WANG En-Bo. Synthesis,Characterization and Activity of a New Type Layered Microporous Materials──Pillared Anion Clay with Ga-W₉-Co₃[J]. Chem. J. Chinese Universities, 1995, 16(12): 1844.

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Synthesis,Characterization and Activity of a New Type Layered Microporous Materials──Pillared Anion Clay with Ga-W₉-Co₃

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