The Phase-Transfer Chemistry of Heteropolyanions(Ⅳ)─The Coordination Reaction of Heteropolyanions with NO

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (9): 1285.

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The Phase-Transfer Chemistry of Heteropolyanions(Ⅳ)─The Coordination Reaction of Heteropolyanions with NO

WANG En-Bo, LIU Xia, WANG Zuo-Ping, XU Lin, GAO Li-Jaun

Department of Chemistry, Northeast Normal Universtity, Changchun, 130024

Received:1993-09-28 Revised:1994-01-30 Online:1994-09-24 Published:1994-09-24

Abstract

Abstract: In this paper, the coordination reaction between the substituted heteropolyanionswith Keggin structure{[XM₁₁O(39)Z]^n-, X=Si, P;M=Mo, W;Z=Co(²⁺), Ni(²⁺)}, and Dawson structure{[P₂W₁₇O₆₁Co]^8-} and the small inorganic molecules nitrogen oxide in a nonpolar solvent is studied by means of the phase-transfer chemistry of heteropolyanions, electronic absorption spectra and electron spin resonance (ESR).The experimental results show that, except the heteropolyanions for [PMo₁₁O(39)Co]^5-, the others can form coordination compounds with nitrogen oxide.

Key words: Heteropolyanions, Phase-transfer, NO coordination

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WANG En-Bo, LIU Xia, WANG Zuo-Ping, XU Lin, GAO Li-Jaun. The Phase-Transfer Chemistry of Heteropolyanions(Ⅳ)─The Coordination Reaction of Heteropolyanions with NO[J]. Chem. J. Chinese Universities, 1994, 15(9): 1285.

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The Phase-Transfer Chemistry of Heteropolyanions(Ⅳ)─The Coordination Reaction of Heteropolyanions with NO

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